（2019）新人教版高中化学选择性必修一第二章第1节化学反应速率第1课时进阶检测（原卷+解析版）.rar

1、第二章第 1 节 化学反应速率第 1 课时 化学反应速率【随堂检测】1. . .“”(1).化学反应.反应速率.反应.(.)(2)化学反应速率. 0.8 molL.1s.1. 1 s 时. 0.8 molL.1(.)(3). v.速率.反应.时.时.(.)ct(4).化学反应.反应速率.(.)(5).反应 2SO2(g).O2(g).2SO3(g).t1.t2时.SO3(g). c1.c2. t1.t2时.SO3(g).速率. v.(.)c2c1t2t12.反应 N2.3H2.2NH3.时.NH3. 0.6 molL.1.时. H2.反应速率. 0.45 molL.1s.1.时.(.)A.1

2、s B.2 sC.44 s D.1.33 s3. 6.5 g .(.). 40 mL 2.5 molL.1. H2.时 10 s 时. 50 mL(. 0 .101 kPa . H2. 44.8 mL).(.)A. 10 s .反应.速率. 0.013 gs.1B.化. H. 10 s .反应.速率. 0.01 molL.1s.1进阶检测step by stepC.化. Zn2. 10 s .反应.速率. 0.01 molL.1s.1D. H2. 10 s .反应.速率. 0.000 2 mols.14.A . B 反应. C.反应速率. v(A).v(B).v(C). 3v(B).2v(A)

3、.2v(C).3v(B).反应.(.)A.2A.3B=2C B.A.3B=2CC.3A.2B=3C D.A.B=C5. 2 L . A.B .反应.3A(g).bB(g).cC(g).H.Q kJmol.1(Q.0).12 s 时反应. C . 0.8 mol.反应. A.B .时.化.(.)A. 12 s .A .反应速率. 0.025 molL.1s.1B.12 s .A .速率. B .速率C.化学. b.c.1.2D.12 s .A . B 反应. 0.2Q kJ6. 2 L .反应.mX(g).nY(g).pZ(g).qQ(g). m.n.p.q .化学. 0.3 min .化.时.

4、XYZQ./mol0.712 min ./mol0.82.70.82.73 min ./mol0.8. 2 min . v(Q).0.075 molL.1min.1. .vZvY12(1).时 n(Y)._.n(Q)._.(2)化学. m._.n._.p._.q._.(3). Z . 2 min .反应速率._.(4)2 min . Q .化率._.【基础再现】1. 0.6 mol X . 0.4 mol Y . 2 L .反应 3X(g).Y(g).nZ(g).2W(g).5 min . 0.2 mol W. Z .化.反应速率. 0.01 molL.1min.1.反应. Z .化学. n

5、.(.)A.1 B.2 C.3 D.42.化学反应速率.(.).化学反应.(.时.)A2NO2(g).N2O4(g).BZn.H2SO4= ZnSO4.H2.H2.化CCO(g).H2O(g)= CO2(g).H2(g).化DCa(OH)2.Na2CO3= CaCO3.2NaOH.化3.(2020.). 5.6 g . 100 mL 2 molL.1.2 min 时.反应. 0.2 min .反应.速率.(.)A.v(Fe).0.5 molL.1min.1 B.v(H2SO4).1 molL.1min.1C.v(H2).1 molL.1min.1 D.v(FeSO4).0.5 molL.1mi

6、n.14.反应 A(g).3B(g).2C(g).2D(g).反应速率.v(A).0.45 molL.1s.1 .v(B).0.6 molL.1s.1.v(C).0.4 molL.1s.1 .v(D).0.45 molL.1s.1.反应.(.)A. B.C. D.5. 4 mol A . 2 mol B . 2 L .反应.2A(g).B(g).2C(g). 2 s . C . 0.6 molL.1. A .反应.速率. 0.3 molL.1s.1. B .反应.速率. 0.6 molL.1s.1.2 s .时. B . 0.7 molL.1.2 s . A .化率. 70%.(.)A. B.

7、C. D.6. 6 mol CO2. 8 mol H2. 2 L .(.).反应 CO2(g).3H2(g).CH3OH(g).H2O(g).H.0. H2.时.化.(.应.).反应. 3.8 min . CO2.反应速率.(.)A.0.5 molL.1min.1 B.0.1 molL.1min.1C.0 D.0.033 molL.1min.17. CaCO3. 100 mL .反应. CO2.(CO2.).(.)A.OE .反应速率.B.EF .反应.反应速率. 0.4 molL.1min.1C.OE.EF.FG .反应.化.反应速率. 2.6.7D.F . CO2.【能力提升】1. NH4

8、I . 2 L .反应.NH4I(s).NH3(g).HI(g).2HI(g).H2(g).I2(g).2 min . H2. 1 mol.HI . 8 mol. NH4I .速率. v(NH3).速率.(.)A.1.25 molL.1min.1 B.2 molL.1min.1C.2.5 molL.1min.1 D.5 molL.1min.12.反应.4FeS2.11O22Fe2O3.8SO2.= = = = =高温 (1).反应.化学反应速率_(.化学.).(2). SO2.速率. 0.64 molL.1s.1时.速率._.(3). 4 s . O2. 2.8 molL.1.时. SO2.反

9、应速率. 0.4 molL.1s.1.时._.3. CO2. CO2.CO2(g).3H2(g).CH3OH(g).H2O(g).学. 6 mol CO2. 8 mol H2. 2 L . H2.时.化.a.b.c.d.e .(1)a.b.b.c.c.d.d.e .反应速率.时._.时. H2.反应速率._.(2)H2.时.CO2.化率._.反应._.4.化.反应.2SO2(g).O2(g).2SO3(g).(1).化学反应速率_(.“.” “.”.“.”).(2)600 .时. 2 L .化.反应. 10 min . 20 min 时.反应.反应. SO2.O2.SO3.化. 10 min

10、.反应速率._(.“.” “.”.“.”). 15 min . SO3.反应速率._.(3).反应.反应速率.反应速率.时._.(4).10 min 时.反应._(.).20 min 时.反应._.a.化.b.c.d. O2.第二章第 1 节 化学反应速率第 1 课时 化学反应速率【随堂检测】1. % %“”(1)%化学反应%反应速率%反应%(%)(2)化学反应速率% 0.8 molL%1s%1% 1 s 时% 0.8 molL%1(%)(3)% v%速率%反应%时%时%(%)ct(4)%化学反应%反应速率%(%)(5)%反应 2SO2(g)%O2(g)%2SO3(g)%t1%t2时%SO3(

11、g)% c1%c2% t1%t2时%SO3(g)%速率% v%(%)c2c1t2t1%(1)%(2)%(3)%2.%反应 N2%3H2%2NH3%时%NH3% 0.6 molL%1%时% H2%反应速率% 0.45 molL%1s%1%时%(%)A%1 s B%2 sC%44 s D%1.33 s%B% H2%反应速率% 0.45 molL%1s%1% NH3%反应速率%v(NH3)%v(H2) % 0.45 molL%1s%1%0.3 molL%1s%1% %t%2 s %23230 . 6 m o l L %10 . 3 m o l L %1s %13% 6.5 g %(%)% 40 mL

12、 2.5 molL%1% H2%时 10 s 时% 50 mL(% 0 %101 kPa % H2% 44.8 mL)%(%)进阶检测step by stepA% 10 s %反应%速率% 0.013 gs%1B%化% H% 10 s %反应%速率% 0.01 molL%1s%1C%化% Zn2% 10 s %反应%速率% 0.01 molL%1s%1D% H2% 10 s %反应%速率% 0.000 2 mols%1%C%0 %101 kPa%H2% 44.8 mL% 0.002 mol%Zn%H2SO4= = =ZnSO4%H2%反应%Zn%H2SO4%ZnSO4%H2%n(Zn)|%n(

13、H2SO4)|%n(ZnSO4)|%n(H2)| %0.002 mol%m(Zn)|%0.002 mol65 gmol%1%0.13 g %v(Zn)%0.013 gs%1%v(H%) %0 . 13 g10 s%0.01 molL%1s%1%v(Zn2 %) %0.005 molL%1s%1%v(H2) %0 . 0 0 2 m o l 20 . 0 4 L 10 s0 . 0 0 2 m o l0 . 0 4 L 10 s%0.000 2 mols%10 . 0 0 2 m o l10 s4%A % B 反应% C%反应速率% v(A)%v(B)%v(C)% 3v(B)%2v(A)%2v(

14、C)%3v(B)%反应%(%)A%2A%3B=2C B%A%3B=2CC%3A%2B=3C D%A%B=C%C% 3v(B)%2v(A)%2v(C)%3v(B)% % %v%v%v(C)v%A %v%B %32v%B %v%C %23%速率%化学%5% 2 L % A%B %反应%3A(g)%bB(g)%cC(g)%H%Q kJmol%1(Q%0)%12 s 时反应% C % 0.8 mol%反应% A%B %时%化%(%)A% 12 s %A %反应速率% 0.025 molL%1s%1B%12 s %A %速率% B %速率C%化学% b%c%1%2D%12 s %A % B 反应% 0.

15、2Q kJ%C% 12 s % A %化% %c(A)%0.2 molL%1%0.8 molL%1%0.6 molL%1%反应速率v(A)%0.05 molL%1s%1%A % 12 s%c%A %t0 . 6 m o l L %112 s% B %化% %c(B)%0.3 molL%1%0.5 molL%1%0.2 molL%1%反应速率v(B)%c%B %t% molL%1s%1%v(C)% molL%1s%1%速0 . 2 m o l L %112 s16 0%c%C %t%n%C %V%t0 . 8 m o l2 L12 s13 0率%化学% %b%c%b%1%c%2 %b%c%1%

16、%C %16 013 0%反应%化学% 3A(g)% A %B 化学%12 s %A%速率% B %速率%B %3 mol A %反应%Q kJ,12 s % A 反应%(0.8 molL%1%0.2 molL%1)2 L %1.2 mol% 1.2 mol A 反应% 0.4Q kJ%D %6% 2 L %反应%mX(g)%nY(g)%pZ(g)%qQ(g)% m%n%p%q %化学% 0%3 min %化%时%XYZQ%/mol0.712 min %/mol0.82.70.82.73 min %/mol0.8% 2 min % v(Q)%0.075 molL%1min%1% %vZvY12

17、(1)%时 n(Y)%_%n(Q)%_%(2)化学% m%_%n%_%p%_%q%_%(3)% Z % 2 min %反应速率%_%(4)2 min % Q %化率%_%(1)2.3 mol%3.0 mol%(2)1%4%2%3%(3)0.05 molL%1min%1%(4)10%时%化学反应速率%化学%化学% X % 2 min %反应%n(Q)%v(Q)Vt%0.075 molL%1min%12 L2 min%0.3 mol%反应%“%”%mX(g)%nY(g)pZ(g)%qQ(g)%/mol% 0.7% n(Y)%1% n(Q)%/mol %n(X) n(Y) n(Z) n(Q)2 mi

18、n %/mol 0.8 2.7 0.8 2.7% n(X)%0.8 mol%0.7 mol%0.1 moln(Z)%0.8 mol%1 mol%0.2 moln(Q)%0.3 mol%2.7 mol%3.0 mol(1)%vZvY|nZ|nY|0.2 molnY12|n(Y)|%0.4 moln(Y)%2.7 mol%0.4 mol%2.3 mol(2)mnpq%|n(X)|n(Y)|n(Z)|n(Q)|%0.1 mol0.4 mol0.2 mol0.3 mol%1423%(3)% %v(Q)%0.075 molL%1min%1% v(Z)%0.05 molL%1min%1%vQvZ32(4)

19、Q %化率 (Q)%100%100%10%nQnQ0.3 mol3.0 mol【基础再现】1% 0.6 mol X % 0.4 mol Y % 2 L %反应 3X(g)%Y(g)%nZ(g)%2W(g)%5 min % 0.2 mol W% Z %化%反应速率% 0.01 molL%1min%1%反应% Z %化学% n %(%)A%1 B%2 C%3 D%4%A%v(W)%0.02 molL%1min%1% Z %化%反应速率%0 . 2 m o l2 L 5 m i n0.01 molL%1min%1% W % Z %化学% %1 %n%1% A %2%化学反应速率%(%)%化学反应%(

20、%时%)A2NO2(g)%N2O4(g)%BZn%H2SO4= ZnSO4%H2%H2%化CCO(g)%H2O(g)= CO2(g)%H2(g)%化DCa(OH)2%Na2CO3= CaCO3%2NaOH%化%C%化学反应速率%时%反应%2NO2(g)%2O4(g)%NO2%N2O4%时%化%反应%A %时%化%反应% B %反应%反应%反应% C %时%速率% D %3%(2020%)% 5.6 g % 100 mL 2 molL%1%2 min 时%反应% 0%2 min %反应%速率%(%)A%v(Fe)%0.5 molL%1min%1 B%v(H2SO4)%1 molL%1min%1C

21、%v(H2)%1 molL%1min%1 D%v(FeSO4)%0.5 molL%1min%1%D%反应 Fe%H2SO4= = =FeSO4%H2%2 min 时 5.6 g (0.1 mol) Fe % 0.1 mol H2SO4% 0.1 mol H2% 0.1 mol FeSO4%Fe %化%反应速率%A %0 %2 min%化%1 molL%1% 0 %2 min%v(H2SO4) %0.5 0 . 1 m o l0 . 1 L1 m o l L %12 m i nmolL%1min%1%B %C %0 %2 min%FeSO4%化%1 0 . 1 m o l0 . 1 LmolL%

22、1% 0 %2 min%v(FeSO4) %0.5 molL%1min%1%D %1 m o l L %12 m i n4%反应 A(g)%3B(g)%2C(g)%2D(g)%反应速率%v(A)%0.45 molL%1s%1 %v(B)%0.6 molL%1s%1%v(C)%0.4 molL%1s%1 %v(D)%0.45 molL%1s%1%反应%(%)A% B%C% D%D%化学反应%反应速率%化学反应速率%化学%反应速率%0.45 molL%1s%1%0.2 v%A %1v%B %3molL%1s%1%0.2 molL%1s%1%0.225 molL%1s%1%反应%v%C %2v%D

23、%2%反应速率% D %5% 4 mol A % 2 mol B % 2 L %反应%2A(g)%B(g)%2C(g)% 2 s % C % 0.6 molL%1% A %反应%速率% 0.3 molL%1s%1% B %反应%速率% 0.6 molL%1s%1%2 s %时% B % 0.7 molL%1%2 s % A %化率% 70%(%)A% B%C% D%答案%B解析2 s % C % 0.6 molL%1% 2 s % n(C)%0.6 molL%12 L%1.2 mol% 2A(g)%B(g)%2C(g)%/mol 4 2 0%化/mol 1.2 0.6 1.22 s %/mol

24、 2.8 1.4 1.2v(A)%0.3 molL%1s%11.2 mol2 L 2 sv(B)%0.15 molL%1s%10.6 mol2 L 2 sA %化率%100%30%1.2 mol4 mol2 s %时 B % c(B)%0.7 molL%1%1.4 mol2 L6% 6 mol CO2% 8 mol H2% 2 L %(%)%反应 CO2(g)%3H2(g)%CH3OH(g)%H2O(g)%H%0% H2%时%化%(%应%)%反应% 3%8 min % CO2%反应速率%(%)A%0.5 molL%1min%1 B%0.1 molL%1min%1C%0 D%0.033 molL

25、%1min%1答案%D7% CaCO3% 100 mL %反应% CO2%(CO2%)%(%)A%OE %反应速率%B%EF %反应%反应速率% 0.4 molL%1min%1C%OE%EF%FG %反应%化%反应速率% 2%6%7D%F % CO2%B%时% CO2%反应速率%时%EF % CO2% EF %反应速率%A % EF % CO2%672 mL%224 mL%448 mL% 0.02 mol% CaCO3%2HCl= = =CaCl2%CO2%H2O %反应% HCl% 0.04 mol%化%0.4 molL%1% EF %反应%反0 . 0 4 m o l0 . 1 L应速率%

26、0.4 molL%1min%1%B %OE %EF%FG % CO2% 224 0 . 4 m o l L %11 m i nmL%448 mL%112 mL%OE %EF%FG %反应% CO2%反应速率% 224 % %11% mL%1%C %G % 784 mL %反应% G % CO2%D %【能力提升】1% NH4I % 2 L %反应%NH4I(s)%NH3(g)%HI(g)%2HI(g)%H2(g)%I2(g)%2 min % H2% 1 mol%HI % 8 mol% NH4I %速率% v(NH3)%速率%(%)A%1.25 molL%1min%1 B%2 molL%1min

27、%1C%2.5 molL%1min%1 D%5 molL%1min%1%C%2 min% H2% HI % 0.5 molL%1%4 molL%1%反应%化%化%化%化%c(HI)%2c(H2) %4 molL%1%20.5 molL%1%5 molL%1% 2 min%化%c(NH3) %c%(HI)%5 molL%1%反应速率% 2.5 molL%1min%1% C %2%反应%4FeS2%11O22Fe2O3%8SO2%= = = = =高温 (1)%反应%化学反应速率_(%化学%)%(2)% SO2%速率% 0.64 molL%1s%1时%速率%_%(3)% 4 s % O2% 2.8

28、 molL%1%时% SO2%反应速率% 0.4 molL%1s%1%时%_%(1)O2%SO2%(2)0.88 molL%1s%1(3)5.0 molL%1%(1)%反应速率% O2%SO2%反应%反应速率%(2)%反应速率%应%化学%速率% 0.64 molL%1s%1%0.88 molL%1s%1%118(3)%时% SO2%速率% 0.4 molL%1s%1%速率% 0.4 molL%1s%1%1180.55 molL%1s%1%化% 0.55 molL%1s%14 s %2.2 molL%1%时% 2.8 molL%1%2.2 molL%1%5.0 molL%1%3% CO2% CO

29、2%CO2(g)%3H2(g)%CH3OH(g)%H2O(g)%学% 6 mol CO2% 8 mol H2% 2 L % H2%时%化%a%b%c%d%e %(1)a%b%b%c%c%d%d%e %反应速率%时%_%时% H2%反应速率%_%(2)H2%时%CO2%化率%_%反应%_%(1)a%b %1 molL%1min%1%(2)33.3%(1)a%b %反应速率%1 molL%1min%1%b %c %反应速8 m o l %6 m o l2 L 1 m i n率%0.75 molL%1min%1%c %d %反应速率%0.1 6 m o l %3 m o l2 L 2 m i n3

30、m o l %2 m o l2 L 5 m i nmolL%1min%1%反应速率%时% a %b %时% H2%反应速率% 1 molL%1min%1%(2)%时% 2 mol%3H2(g)%CO2%3OH(g)%H2O(g)%/mol% 8 %6 %0 % 0%化%/mol 6 2 2 2%/mol 2 4 2 2%时 CO2%化率%1%时%2 m o l6 m o l%反应%(6%2 %2 %2)%4%化%反应%2SO2(g)%O2(g)%2SO3(g)%(1)%化学反应速率_(%“%” “%”%“%”)%(2)600 %时% 2 L %化%反应% 10 min % 20 min 时%反

31、应%反应% SO2%O2%SO3%化% 10 min %反应速率%_(%“%” “%”%“%”)% 15 min % SO3%反应速率%_%(3)%反应%反应速率%反应速率%时%_%(4)%10 min 时%反应%_(%)%20 min 时%反应%_%a%化%b%c%d% O2%(1)%(2)%1.3310%3 molL%1min%1%(3)15%20 min,25%30 min%(4)ab%d%(2)% 10 min%反应%反应速率% 15 min%化% 0.04 mol%化% 0.02 molL%1% SO3%反应速率% 0.02 molL%115 %1%1%3 molL%1min%1%(3)%反应% 15 %20 min%25%30 min%反应%(4)% 10 min时%率%反应速率%化%20 min时% O2%