路博润金属加工液培训课件.pptx

1、 The Lubrizol Corporation 2006,all rights reservedMetalworking Additives金属加工添加剂金属加工添加剂October 2021 The Lubrizol Corporation 2007,all rights reservedAgenda 议程 Introduction 概况介绍 Metalworking Capabilities and Support 金属加工系列产品线和技术支持 Product Offering and Formulation Advices 产品介绍和配方举例 Questions 问题 The Lub

2、rizol Corporation 2007,all rights reservedLubrizolLockhart-Locksol-Lockguard Becher Chemie-Becrosan-Contram-SkosanorAlox-Aqualox-Alox Gateway-Addco-Synester-AddconateLubrizol MetalworkingBrand NamesSulfurized EP Additives,Traditional Soluble Oil Emulsifier硫系极压剂及乳化剂产品硫系极压剂及乳化剂产品Waterbased Additives,E

3、mulsifier Expertise,Speciality Polymeric Esters水基添加剂、乳化剂和聚合酯水基添加剂、乳化剂和聚合酯Water based Additives,Corrosion Inhibitor Expertise,水基防锈及防腐水基防锈及防腐蚀剂蚀剂Biocides杀菌剂杀菌剂Rust Preventives,Water based Corrosion Inhibitors防锈剂防锈剂Rust Preventives,Natural Sulfonate supply,Thixotropic Gelled Sulfonate防锈剂、磺酸盐防锈剂、磺酸盐 The

4、 Lubrizol Corporation 2007,all rights reservedGlobal Support 全球技术支持 Technical laboratories 技术实验室 Wickliffe,OH USA Brecksville,OH USA Hazelwood,England Spartanburg,SC USA Metalworking Research&Technical Service金属加工产品研发和技术支持金属加工产品研发和技术支持 Hamburg,Germany 德国汉堡德国汉堡 Metalworking Technical Support 金属加工产品技术

5、支持金属加工产品技术支持 Shanghai,China 上海上海 Metalworking Technical Support 金属加工产品技术支持金属加工产品技术支持 The Lubrizol Corporation 2007,all rights reservedShanghai Metalworking Resources上海实验室配置和评价方法ProcedureProperty EvaluatedIP287 Filter Paper Chip Breakpoint 防锈/滤纸铁屑法IP263Emulsion Stability 乳化安定性IP 311Concentrate Storag

6、e Stability 储存稳定性IP312Foam Test Shaking Method 泡沫试验ASTM D 455Kinetic Viscosity 黏度测定Lubrizol Pump Test Foam Test 路博润泡沫试验MicroTap II Lubricity 润滑性评定/攻丝扭矩Mod.Timken Fish Tank Bacteria Resistance 抗菌性试验If need technical service for our customers,pls fill in TSRs first.MicroTapFoam Rig The Lubrizol Corpor

7、ation 2007,all rights reservedAdditives Applications Capabilities路博润添加剂的应用领域Cleaners清洗剂清洗剂 Metal Removal切削切削 Metal Forming 成型成型 Process Additives 工艺助剂工艺助剂 Rust Preventives防锈防锈 Industrial Additives 工业用油工业用油 Corrosion Inhibitors 腐蚀抑制腐蚀抑制Internal Lubrication润滑润滑 Lubrizol Metalworking Additives The Lubr

8、izol Corporation 2006,all rights reservedMetalworking AdditivesProduct Offering for Water based Products水基金属加工液产品介绍水基金属加工液产品介绍 The Lubrizol Corporation 2007,all rights reservedMetalworking Additives金属加工添加剂 Water Based Water Miscible 水基或水溶性产品 Aqueous Fluid System 应用于水基体系 Generally Supplied as Concent

9、rate for Dilution in Water 通常以浓缩液的形态供给，使用时以水稀释 Sub Categories 这类产品包括 Soluble Oil 乳化油 Synthetic 全合成液 Semi Synthetic 半合成液 The Lubrizol Corporation 2007,all rights reservedProduct Categories 产品 Emulsifier Components Emulsifier Packages Hong Jing 乳化复合剂洪泾介绍 Extreme Pressure Additives Lubricity Additives

10、润滑剂 Rust Preventives Corrosion Inhibitors 防锈剂 Industrial Metalworking Biocides 杀菌剂 The Lubrizol Corporation 2007,all rights reservedLubricity Additives for water miscible fluids水基润滑剂水基润滑剂 The Lubrizol Corporation 2007,all rights reservedLubricity/EP agents 润滑/极压剂 ADDOSAN ESTEP 206 TMP-Ester of Casto

11、roil and Oleicacid 是以蓖麻油和油酸为原料的是以蓖麻油和油酸为原料的TMP的酯的酯 Addosan ESTEP 206 is used as an EP-additive in water miscible metal working fluids,especially for Al-processing.Typical treat levels in the concentrate should be 5-10%.该产品可用于水基配方中做极压剂，特别适合铝加工。该产品可用于水基配方中做极压剂，特别适合铝加工。加量加量510%For the machining of stee

12、l the addition should be between 5 and 20%to the concentrate,depending on the requirements and the severity of the process 用于钢材加工时需要在浓缩液里参加用于钢材加工时需要在浓缩液里参加520%，视加工，视加工的剧烈程度而定。的剧烈程度而定。In non water based metal working fluids,Addosan ESTEP 206 is qualified for fine steel wire drawing in combination wit

13、h P-EP and S-additives.在非水基的体系中它与含磷或含硫极压剂共用可用于细在非水基的体系中它与含磷或含硫极压剂共用可用于细钢线的拉拔。钢线的拉拔。Addosan ESTEP 206 can also be used as a fatty agent in non-water miscible metal working fluids.在非水溶性配方里可用作油性剂在非水溶性配方里可用作油性剂 It is also suitable for grinding processes where a good stability of the fatty component is r

14、equired.在磨削加工中如果需要使用稳定性好的油性剂，可考虑使在磨削加工中如果需要使用稳定性好的油性剂，可考虑使用该产品用该产品 The Lubrizol Corporation 2007,all rights reservedAddosan Estep 206 Properties Colour颜色:ligth brown 浅棕色Acid value 酸值(mg KOH/g):max 10Viscosity 黏度(40 C):appr 85 mm/s Typical use level典型用量 Waterbased水基:5 10%Neat oils油基:1 2%(neat oils:2%

15、Estep 206+0.5%EPC 127 -used for flute grinding 在油基配方中使用2%Estep 206+0.5%EPC 127可用于成管加工)The Lubrizol Corporation 2007,all rights reservedBECROSAN E 2135 amine and boron free formulation with biocide配方举例：不含胺、不含硼的半合成液配方配方举例：不含胺、不含硼的半合成液配方BECROSAN E 2135 45%Addosan ESTEP 206 10%Naphthenic Base Oil 42%CON

16、TRAM OF-G 2.5%CONTRAM J 30 D 0.5%An approx.8%emulsion of a preparation of BECROSAN E 2135,performance ester(in particular Addosan ESTEP 206)in base oil(as above)works extraordinary well for general aluminium machining.上述配方以上述配方以8%的稀释液用于铝加工具有非常突出的效果的稀释液用于铝加工具有非常突出的效果 Appearance 外观 visual目测 translucen

17、t 半透明 Emulsion stability 乳化安定性 visual after 24 hrs 0 ml oil/0 ml creampH value,5%in water 5%水溶液的PH值 DIN 51 3699.1 Corrosion protection DIN 51 360 part 2 Note 0 at 4%vol 防锈 The Lubrizol Corporation 2007,all rights reservedSemi Synthetic Aluminum铝加工半合成液润滑效果45%BECROSANE2135+环烷基油 VS 10%ADDOSANESTEP206+4

18、5%BECROSANE2135+环烷基油 The Lubrizol Corporation 2007,all rights reservedHigh oil-Semi-Synthetic Packages与高含油半合成复合剂的复配配方Base oil 基础油基础油41.7045.7050.70BECROSAN E 2137 H/LUBRIZOL 568342.00-BECROSAN E 2135-40.00-BECROSAN E 2152-35.00ADDOSAN ESTEP 20610.010.010.0CONTRAM MBO or ST-12.002.002.00CONTRAM J 30

19、D0.300.300.30Quicklin 131.00-Water 水水3.00-TD 25/30-2.002.00LUBRIZOL 5674 消泡剂消泡剂0.10-0.10 The Lubrizol Corporation 2007,all rights reservedPerformance 性能E 2137 H/LUBRIZOL 5683E 2135E 2152Appearance 外观外观yelow-light brown,clear黄色淡棕色，透明Yelow light brown,clear黄色淡棕色，透明Yellow light brown,clear黄色淡棕色，透明Appea

20、rance emulsion(5%in 20dH)乳液外乳液外观观Fresh新鲜乳液Translucent 半透明Translucent 半透明Translucent半透明after 24 h24小时后translucent-no cream半透明无浮皂translucent-no cream半透明无浮皂translucent-no cream半透明无浮皂corrosion -DIN 51360-part 2 防锈防锈2%-class 0-12%-class 1-22%-class 2corrosion -IP 287 防锈防锈breakpoint 2%breakpoint 3%breakpo

21、int 3%pH-value-(5%in 20dH)pH值值9.209.409.40foam characteristic 泡 沫5%in 10dHno foam 无泡沫no foam 无泡沫no foam无泡沫5%in 5dH70 ml-10 ml-0 ml50 ml-0 ml-0 ml70 ml-10 ml-0 mlReichert without lubricity 磨斑磨斑/未加润滑剂未加润滑剂30.0 mm31.3 mm33.2 mmReichert with 磨斑磨斑/加入加入ADDOSAN ESTEP 206 The Lubrizol Corporation 2007,all r

22、ights reservedMetalworking-Corrosion Inhibitors 防锈剂 The Lubrizol Corporation 2007,all rights reservedBecrosan 2131 TechnologyTrivial name:Triazinetrisaminohexanoic acid三嗪三氨基己酸三嗪三氨基己酸 IUPAC:6,6,6-(1,3,5-triazine-2,4,6-triyltriimino)-trihexanoic acidNNNCOOHNNCOOHNHOOCCAS-No.80584-91-4 MW:468.6 g/mol T

23、he Lubrizol Corporation 2007,all rights reservedBecrosan 2131 TechnologyApplications应用应用Neutralized with alkali/alkanolamine performs as very effective corrosion inhibitor用碱用碱/醇胺中和后是非常有效的腐蚀抑制剂醇胺中和后是非常有效的腐蚀抑制剂Applied in all types of water based systemsMetalworking fluids(Semi-synthetic and synthetic

24、fluids)可以用于所有类型的水基体系金属加工液可以用于所有类型的水基体系金属加工液(半合成和合成液半合成和合成液)High water based hydraulic fluids(HFC)可用于高水基液压液可用于高水基液压液(HFC)Engine and other cooling systems 用于发动机和其他冷却体系用于发动机和其他冷却体系 The Lubrizol Corporation 2007,all rights reservedBecrosan 2131 TechnologyBenefits优点优点Very effective corrosion inhibition高效

25、防锈高效防锈Does not form resinous films or gums on metals 不会在金属外表形成树脂或胶状膜不会在金属外表形成树脂或胶状膜Low foaming低泡沫低泡沫No aluminum staining(depending on amine used)不会造成铝腐蚀不会造成铝腐蚀Compatible with hard water up to 2000 ppm 耐硬水能力高达耐硬水能力高达 2000 ppmCan be used for corrosion inhibition of multi-metal systems,might be improve

26、d by addition of Skosanor KSP 24/531 and heptanoic/ison.Acid 可以用于含多种金属的体系，添加可以用于含多种金属的体系，添加Skosanor KSP 24/531可提高防腐蚀效果可提高防腐蚀效果PROVEN:No tendency to form nitrosamines(5f rule in US)不会生成亚硝胺不会生成亚硝胺Excellent air release良好的空气释放性能良好的空气释放性能 The Lubrizol Corporation 2007,all rights reservedBecrosan 2128 Tec

27、hnologyTrivial name:Tolylsulfonamidohexanoic acid对甲苯磺酰氨基己酸对甲苯磺酰氨基己酸 IUPAC:4-Methylphenylsulfonylaminohexanoic acidSOONH3CCOHOHCAS-No.78521-39-8 MW:285.0 g/mol The Lubrizol Corporation 2007,all rights reservedBecrosan 2128 TechnologyApplications应用应用:Neutralized with alkali/alkanolamine performs as ve

28、ry effective corrosion inhibitor用碱用碱/醇胺中和后是非常有效的腐蚀抑制剂醇胺中和后是非常有效的腐蚀抑制剂Applied in all types of water based systems Metalworking fluids(Semi-synthetic and synthetic)可以用于所有类型的水基体系金属加工液可以用于所有类型的水基体系金属加工液(半合成和合成液半合成和合成液)Water treatment processes水处理过程水处理过程Press waters水压系统水压系统Industrial cleaners工业清洗剂工业清洗剂Of

29、f-shore lubricants海上石油海上石油/天然气钻探用润滑剂天然气钻探用润滑剂Water based hydraulic fluids水基液压液水基液压液Water/glycol cooling systems(+KSP 24/531)水水/乙二醇冷却体系可参加乙二醇冷却体系可参加 KSP 24/531提高抗腐蚀效果提高抗腐蚀效果 The Lubrizol Corporation 2007,all rights reservedBecrosan 2128 TechnologyBENEFITSVery effective corrosion inhibition for ferrou

30、s metals,cast iron,ferrous alloys at a pH value of 8.pH值值8时，对铁、铸铁和铁合金的防锈非常有效时，对铁、铸铁和铁合金的防锈非常有效Easy handling,easy soluble,non dusting,odorless 容易使用，容易溶解容易使用，容易溶解,不会产生粉尘，不会产生粉尘，无味无味 No sticky residues after water phase evaporation 水相挥发后无粘性残留物水相挥发后无粘性残留物Low foaming低泡低泡Compatible with hard water up to 2

31、000 ppm耐硬水能力耐硬水能力 2000 ppmNo staining on aluminum(depending on amine used)不会造成铝变色不会造成铝变色No tendency to form nitrosamines不会生成亚硝胺不会生成亚硝胺Higher thermal stability than metal soaps比金属皂具有更好的热稳定性比金属皂具有更好的热稳定性 The Lubrizol Corporation 2007,all rights reservedFully synthetic based on BECROSAN 2131全合成液的建议配方20

32、%Triethanolamine 三乙醇胺5%Monoethanolamine 单乙醇胺16%BECROSAN 21312,5%Isononanoic acid 异壬酸0,5%Skosanor KSP 5310,5%CONTRAM NFK55,5%Water 水DIN 51360 T2(Chip filter test)防锈滤纸铁屑法=2,5%class 0pH-value(3%in DI-water)pH值在3%去离子水中=9,2Foam behaviour(5%in 10dH-water)泡沫 =70 ml 30 ml 0 mlReichert(5%in DI-water,100 m,1,

33、5 kg)磨斑=30,6 mm/GM 100 The Lubrizol Corporation 2007,all rights reservedStarting Formulation Grinding/Machiningmore severe machining用于更高负荷的磨削/切削配方Component成分%By Weight 重量%Triethanolamine三乙醇胺20Monoethanolamine单乙醇胺5BECROSAN 213110Water 水balanceADDCO 410 P5ADDCO MLB 10X10SKOSANOR KSP 5310,5Bactericide/

34、fungicide杀菌剂2-3 The Lubrizol Corporation 2007,all rights reservedSemi synthetic based on BECROSAN 2131半合成配方32,0%Base oil 根底油8,0%ADDCONATE M 15,5%Triethanolamine 三乙醇胺2,0%Monoethanolamine 单乙醇胺7,5%BECROSAN 21282,0%BECROSAN 21312,5%TD 25/30 7,5%Coupling agents(fatty alcohol)偶合剂15,0%Water 水5,0%BECROSAN C

35、656(fatty acid amide脂肪酸酰胺)2,5%CONTRAM ST-10,5%CONTRAM J 30 D Appearance 外观Clear,yellow 黄色透明Emulsion乳液Translucent 半透明DIN 51360 T2(Chip filter test)防锈=2,5%class 0pH-value(3%in DI-water)pH=9,3 The Lubrizol Corporation 2007,all rights reservedUse Of Alkanolamides In Metalworking金属加工液中链烷醇酰胺的应用 Emulsifier

36、 做乳化剂 Functions as a primary or secondary emulsifier in o/w metalworking formulations在水包油型乳化油配方中可做主乳化剂或助乳化剂使用 Lubricity Additive 润滑剂 Amides based on longer chained fatty acids enhance lubrication properties to a fluid基于长链脂肪酸的酰胺有助于提高体系的润滑效果 Corrosion Inhibitor 防锈剂 Fatty acid alkanolamides provide ext

37、ra corrosion protection for ferrous metals脂肪酸的链烷醇酰胺对黑色金属有良好的防锈效果.The Lubrizol Corporation 2007,all rights reservedFatty amides/esters 脂肪酸酰胺/酯STRENGTH 优点优点Cheap corrosion inhibitors 是一种较廉价的防锈剂是一种较廉价的防锈剂Post treatment application possible 可现场添加可现场添加Low classification level。Low toxicity profile 低毒性低毒性S

38、ome are liquid,easy to handle 有一些产品是液体的，易操作有一些产品是液体的，易操作Used for semi-synthetic and soluble oil type fluids 可用于乳化油和半合成液可用于乳化油和半合成液 The Lubrizol Corporation 2007,all rights reservedFatty amides/esters 脂肪酰胺/酯Product产品产品Alk.amine胺的种类胺的种类Appea-rance 外观外观Viscosity 40C黏黏 度度TAN酸值酸值TBN碱值碱值Solubility溶解性溶解性CP

39、-51360/2SOE+2%am.5%in w.(orig:cl.3,0,9,2)防锈（浓缩液中加防锈（浓缩液中加2%，5%稀释）稀释）B.210 EMEAPasty膏状-810Emuls.可乳化cl.2,pH 9.2B.210 MMEAPasty膏状-153Emuls.可乳化cl.2,pH 9.1B.210 RDEALiquid液体3855130Emuls.可乳化cl.1,pH 9.1B.210 D IIDEALiquid液体1701435Emuls.可乳化cl.1-2,pH 9.0B.541MIPLALiquid/pasty液态/膏状15039Emuls.可乳化cl.2,pH 9.0B.C

40、 656DGALiquid液体2005010Soluble可溶cl.1-2,pH 9.2B.228DEALiquid液体39015150Dispers.水分散cl.0-1,pH 9.2B.583TEA/MEALiquid液体2105052Emuls可乳化cl.0-1,pH 9.1B.2021DETAWaxy蜡状45 60C3.524Insol.不溶cl.2,pH 9.2 The Lubrizol Corporation 2007,all rights reservedPerformance 性能18%LUBRIZOL 5475 in 100 N base oil18%LUBRIZOL 5475

41、+2%BECROSAN 583 in 100 N base oil18%LUBRIZOL 5475+4%BECROSAN 583 in 100 N base oilAppearance外观外观yelow-light brown,clear黄色淡棕色，透明Yelow light brown,clear黄色淡棕色，透明Yellow light brown,clear黄色淡棕色，透明Appearance emulsion(5%in 20dH)乳液外观乳液外观0 ml oil/0.3 ml cream0 ml oil/0.1 ml cream0 ml oil/0.1 ml creamcorrosion

42、 -DIN 51360-part 2 防锈防锈5%-class 25%-class 15%-class 0corrosion -IP 287 防锈防锈breakpoint 5,5%breakpoint 4,5%breakpoint 4%pH-value-(5%in 20dH)9.209.409.40foam characteristic泡沫泡沫5%in 10dHno foam无泡沫no foam无泡沫no foam无泡沫5%in 5dH70 ml-10 ml-0 ml100 ml-40 ml-0 ml100 ml-50 ml-0 mlReichert 磨斑磨斑34.0 mm31.3 mm28.

43、2 mm The Lubrizol Corporation 2007,all rights reservedADDCONATE Starting FormulationSemi Synthetic建议起始配方建议起始配方半合成半合成Base oil 基础油基础油30.00ADDCONATE M10.00DEG2.00TEA10.00TD 25/301.00Guerbitol C 162.50BECROSAN(TM)C 6567.50Isononanoic 异壬酸异壬酸1.00Emulsogen M0.50Water 水水35.50Appearance外观Clear yellow liquid黄

44、色透明液体Appearance-emulsion乳液外观Translucent半透明pH-value(3%in 20dH)PH值9.15Corrosion(DIN 51360-2-4%)防锈Class 0-1 The Lubrizol Corporation 2007,all rights reservedADDCONATE Starting FormulationSemi Synthetic 建议起始配方建议起始配方半合成半合成base oil 基础油基础油32.00ADDCONATE M 8.00BECROSAN C 2141(carboxylic acid salt 羧酸盐羧酸盐)25.

45、00TD 25/30 2.50Emulsogen M 5.003370 V2.50Water 水水15.00MEA 2.00BECROSAN C656(Fatty acid amide)5.00CONTRAM ST-1 2.50CONTRAM J 30 D 0.50Appearance 外观Clear yellow liquid黄色透明液体Appearance-emulsion乳液外观Translucent半透明pH-value(3%in 20dH)PH值9.3Corrosion(DIN 51360-2-4%)防锈Class 0 The Lubrizol Corporation 2007,al

46、l rights reservedBiocides杀菌剂杀菌剂 The Lubrizol Corporation 2007,all rights reservedBiocide review:The Lubrizol Corporation 2007,all rights reservedBiocide review:Micro-organisms like微生物喜欢 A wet environment潮湿环境 Temperature温度 Dust尘土 And certain elements as food stuff 以及某些可以作为食物的元素Which are given in allM

47、ETAL WORLKING FLUIDS这些在金属加工液中均可以得到满足这些在金属加工液中均可以得到满足 The Lubrizol Corporation 2007,all rights reservedBiocide review:The Lubrizol Corporation 2007,all rights reservedBactericides杀细菌剂杀细菌剂 The Lubrizol Corporation 2007,all rights reservedCONTRAM ST-1 N,N-methylenebismorpholine N,N-亚甲基双吗啉 CAS#5625-90-1

48、NONO The Lubrizol Corporation 2007,all rights reservedCONTRAM MBO Oxazolidine,3,3-methylenebis5-methyloxazolidine 噁唑烷，3,3-亚甲基双5-甲基唑烷 CAS#66204-44-2ONON The Lubrizol Corporation 2007,all rights reservedProduct Features 产品特性 CONTRAM ST-1 Exceptional stability in MWF concentrates 在浓缩物中特别稳定 Does not dis

49、rupt balance of emulsion system 不会干扰乳液体系的平衡 Long-lasting efficacy(half-life is 5-8 months)长效 半衰期5-8个月 Unique balance of oil and water solubilityimportant feature for emulsion systems 突出的水溶性和油溶性对乳液体系非常重要 Low total formaldehyde content 总甲醛含量低 Evidence for efficacy vs.mycobacteria 对细菌特别有效 No skin irrit

50、ation(no R43)对皮肤刺激性小 不用“贴标签 R43 Easy compatible with common used fungicides(NaPyrion,IPBCs,BBits)容易与抗真菌剂并用 Works quite well in pH ranges 7-11 在pH7-11范围内特别有效 Concentrate treatment:2,5 3,0%浓缩物加剂量 2.5-3.0%Tankside treatment:not preferred 不推荐用于现场添加 Stability problems of CONTRAM ST-1 as sold:solidificati