汽车修补漆树脂Nuplex-Resin-ntroduction课件.ppt

1、2023年1月28日星期六汽车修补漆树脂汽车修补漆树脂Nuplex-Resin-ntroductionVehicle Refinish Paint Layers机车修补涂层示意机车修补涂层示意Metal body 金属车身Clearcoat(60 m)面漆Basecoat(20 m)底漆Primer/Filler中涂(60-150 m)Wash primer磷化蚀洗底漆(10 m)Polyester putty聚酯灰or Monocoat(60 m)Basic functions 基本功能基本功能protection of surface 表面保护leveling,smoothing of r

2、ough surface 流平，修整粗糙表面adhesive layer for topcoat 与面漆层间附着 Resin Requirements 树脂要求树脂要求hardness/flexibility:stone chip resistance 硬度/柔韧性：耐石击性pigment wetting:leveling and appearance 颜料湿润性：流平和外观adhesion:corrosion resistance,no peeling-off of topcoats 附着力：耐腐蚀，防止面漆剥离。drying speed:earlier sanding 干燥速度：尽早打磨l

3、ow price:economics 低价：实惠Vehicle Refinish Primer 汽车修补中涂汽车修补中涂Vehicle Refinish Primer Resins Overview机车修补中涂树脂概况机车修补中涂树脂概况 Solventborne溶剂型Standard标准:Setalux 1184(结合Setalux 1187)fast drying快干:Setalux 1200 good adhesion附着力好:Setalux 1196chemical resistance耐化学性好:Setalux 1152non-isocyanate 2K:Setalux 7202+7

4、002Vehicle Refinish Primer Resins Products(1)汽车修补中涂产品汽车修补中涂产品Setalux 1184 SS-51acrylic polyol with 2.0%OH(on non-volatiles)2.0%羟基丙烯酸very fast drying 非常快干good hardness 硬度好good sandability 打磨性好Setalux 1187 XX-60acrylic polyol with 3.6%OH(on non-volatiles)3.6%羟基丙烯酸very flexible 柔韧性好medium solids 中等固体份V

5、ehicle Refinish Primer Resins Products(2)汽车修补中涂产品汽车修补中涂产品Setalux 1196 XX-60acrylic polyol with 2.6%OH(on non-volatiles)2.6%羟基丙烯酸good adhesion on various substrates 在不同的底材上有好的附着fast drying 快干good chemical resistance 耐化学性好Setalux 1200 XX-55acrylic polyol with 1.8%OH(on non-volatiles)1.8%羟基丙烯酸very fast

6、 drying 非常快干good adhesion on various substrates 在不同的底材上有好的附着good hardnessVehicle Refinish Primer Resins Products(3)汽车修补中涂产品汽车修补中涂产品Setalux 7202aceto-acetate functional acrylic resin 带乙酰乙酸功能丙烯酸树脂Setalux 7002ketimine functional a酮亚胺功能树脂cPrinciple原理原理:The ketimine groups in the crosslinker are deblocke

7、d by traces of water(humidity).The resulting primary amines react very fast with the aceto-acetate groups to form enamine bonds.酮亚胺官能团由水(湿度)的作用交联解块。结果伯胺和酮亚胺官能团反应非常快产生烯胺键。rFeatures:very fast drying and curing resulting in good sanding properties even under severe humidity conditions and low temperatu

8、res 在低温和湿气环境下很快干易打磨。good adhesion 附着好 low toxicity 低毒性:total system 整个体系:LC50 4,84 g/m3 rat individual resins单独树脂:LD50 10 ml/kg ratesin(cross-lir)Vehicle Refinish Primer Resins Formulation 汽车修补中涂树脂配方汽车修补中涂树脂配方 Formulation for a primer with PVC=43%and 100%crosslinking 中涂体积颜基比43%和100%交联。solid binder 1

9、00.0 acrylic polyol+isocyanate 羟基丙烯酸+异氰酸酯Bentone 38 2.5 rheology control 流变助剂Kronos 2190 40.0 hiding power 钛白粉Micro Talc AT Extra 40.0 extender 滑石粉China Clay 90.0 extender 高岭土Heucophos ZP10 30.0 anti-corrosion 磷酸锌Bayferrox 3910 6.0 hiding power 氧化铁黄Dibutyl tin dilaurate 2.5 catalyst 催化剂BYK-141 1.0 d

10、efoamer 消泡剂solvents .溶剂Vehicle Refinish Primer Resins Comparison(2)汽车中涂树脂对比汽车中涂树脂对比Tackfree:time in h:mm with cotton wool methodHardness:Knig hardness in seconds after 7 days 23CVehicle Refinish Primer Resins Comparison(3)汽车中涂树脂对比汽车中涂树脂对比Adhesion:overall relative score of adhesion on several substra

11、tes,wet adhesion and high pressure cleaningSaltspray:blistering rate after 1000 hours exposure on phosphated steel(f=few,m=medium,d=dense)Vehicle Refinish Primer ResinsStarting Point Formulations汽车修补中涂起始配方汽车修补中涂起始配方Solventborne溶剂型 Setalux 1184 REC 97021 Setalux 1184+1187REC 99051 Setalux 1196REC 030

12、09 Setalux 1200 REC 99026 Setalux 7202+7002REC 99015Vehicle Refinish Basecoat 汽车修补底漆汽车修补底漆Basic functionsic 基本功能Aesthetics 美观Resin Requirements 树脂要求pigment wetting/stability:colour matching and in-can stability颜料湿润性/稳定性：色差仪和涂料储存稳定adhesion:intercoat adhesion,no peeling-off between layers附着力：层间附着，层间不分

13、层。film inertness:prevent strike-in of solvents from clearcoatrheology control:metallic particles orientation,optimum flip-flop 防止清漆溶剂咬底，外观控制金属粉定向。thixotropy:no setting of pigment with good spray properties触变性：防止颜料沉降和好的喷涂性能。Vehicle Refinish Basecoat Resins Overview汽车修补底漆概括汽车修补底漆概括Solventborne溶剂型Polye

14、ster聚酯:Setal 173Polyester聚酯:Setal 189polyester SCA mod.:Setal 90173Acrylic丙烯酸:Setalux 1184Acrylic丙烯酸:Setalux 1385Vehicle Refinish Basecoat Resins Products(1)汽车修补底漆树脂产品汽车修补底漆树脂产品Setal 173 VS-60saturated polyester 饱和聚酯good adhesion 附着力好good flexibility 柔韧性好good chemical and water resistance 耐化学和耐水性好Se

15、tal 189 XX-65saturated polyester饱和聚酯good pigment wetting 颜料湿润性好good hardness 高的硬度good compatibility with CAB 与CAB相溶性好Ve hicle Refinish Basecoat Resins Products(2)汽车修补底漆树脂产品汽车修补底漆树脂产品Setal 90173 SS-50-SCA modified saturated polyesters 饱和聚酯改进流变控制剂-prevents settling and sagging 防止沉降和流挂-excellent metall

16、ic orientation 优异的金属定向性-less CAB required(higher solids,cost effective)对CAB需求少-less wax required 对蜡的需求少-good adhesion 附着好-good pigment wetting 颜料湿润性好Vehicle Refinish Basecoat Resins Products(3)汽车修补底漆树脂产品汽车修补底漆树脂产品Setalux 1385 BX-51thermosetting hydroxylated acrylic 热固性羟基丙烯酸树脂very good compatibility

17、with CAB 和醋酸丁酸纤维素有好的相容性fast drying 快干Setalux 1184 SS-51acrylic polyol 羟基丙烯酸good compatibility with CAB 和醋酸丁酸纤维素有好的相容性fast drying 快干Vehicle Refinish Basecoat Resins System examples(1)汽车修补底漆树脂例汽车修补底漆树脂例Polyester 聚酯49 parts Setal 189 XX-6538 parts CAB 381-0.510 parts CAB 551-0.23-5 parts Cerafak 106 or

18、 Ceratix 8461(5 parts Setamine US-138)SCA modified polyester聚酯改进流变控制剂67 parts Setal 9017330 parts CAB 381-0.5 3 parts Cerafak 106Vehicle Refinish Basecoat Resins System examples(2）汽车修补底漆树脂例）汽车修补底漆树脂例Thermosetting acrylic 热固性丙烯酸树脂51 parts Setalux 1385 BX-5138 parts CAB 381-0.5 5 parts Ceratix 8461 6

19、parts Setamine US-138Acrylic polyol 羟基丙烯酸58 parts Setalux 118438 parts CAB 381-0.5 4 parts Cerafak 106Vehicle Refinish Basecoat Preparation(1)汽车修补底漆制备汽车修补底漆制备Solventborne metallic basecoat 溶剂型金属底漆1.dissolve the metallic pigments under slow stirring;add dispersant and rheology control additive低速分散金属颜

20、料和添加分散剂和触变剂2.make a premix of basecoat resins;add the CAB-resin under high shear forces;add the other additives 高速搅拌底漆树脂与CAB的混合基料，添加助剂。3.add the pigment-paste(component 1)under slow stirring bit by bit to component 2 低速搅拌将颜料浆缓慢加入基料，然后高速分散。4.add the solvents till the right delivery form.添加溶剂调整Vehicle

21、 Refinish Basecoat Metallic control汽车修补底漆金属效果控制汽车修补底漆金属效果控制Wet basecoatRandom orientation of Al-platesNo“Flop”铝粉在湿膜中无规则排列Dry basecoatParallel alignment of Al-platesExcellent“Flop”干燥后铝粉有序排列DryingShrinkage of the wet basecoat during drying results in good particle orientation底漆干燥收缩过程中有好的颗粒定向Vehicle Re

22、finish Basecoat ResinsStarting Point Formulations 汽车修补底漆树脂起始配方汽车修补底漆树脂起始配方 Solventborne溶剂型溶剂型 Setal 173REC 01008 Setal 189REC 01010,02032 till 02038 Setal 90173REC 03044,04008 Setalux 1184REC 00031 Setalux 1385REC 04036Vehicle Refinish Clearcoat汽车修补清漆汽车修补清漆Basic function 基本功能基本功能-Protection of basec

23、oat layer against environment 对底层的保护 -Aesthetics 美观 Resin Requirements 树脂要求树脂要求-good gloss,levelling,clarity:overall appearance 光泽，流平：综合外观-chemical resistance:no acid attack 耐化学性：酸侵蚀-weathering resistance:outdoor durability 耐候性：户外耐久性-fast drying/hardness development:earlier handling/polishability快干/

24、硬度：尽早的操作/打磨性-low colour:no problems in colour matching 低的颜色：不影响色差-good adhesion:intercoat adhesion 好的层间附着力Vehicle Refinish Clearcoat Resins Overview汽车修补清漆树脂概括汽车修补清漆树脂概括Solventborne溶剂型Standard标准 :Setalux 1152 SS-51economy grade实惠 :Setalux 1186 SS-60 fast drying快干 :Setalux 1192 SS-60，good appearance外观

25、好 :Setalux 1190 SS-61,Setalux XSZ1107medium solids中等固体 :Setalux 1198 SS-70,Setalux 1215 BA-68high gloss,wetlook高光 :Setalux 1211,Setalux 1753high solids acrylic高固丙烯酸 :Setalux 1901,Setalux 1903high solids polyester高固聚酯 :Setal 1715,Setal 1603Weather resistance 耐候耐黄变:Setalux XSZ 1003 Super fast drying 超

26、快 :Setalux 57-2500Vehicle Refinish Clear coat Resins（1）汽车修补清漆树脂汽车修补清漆树脂Setalux 1152 SS-51standard low solids acrylic polyol with 4.2%OH(on NV)标准低固羟值4.2%丙烯酸good hardness 硬度好good gloss and leveling 光泽和流平好good chemical resistance 耐化学性好Setalux 1186 SS-60low solids acrylic polyol with 3.0%OH(on non-volat

27、iles)低固羟值3.0%丙烯酸good gloss and leveling 光泽和流平好good hardness/flexibility 硬度和柔韧性平衡Vehicle Refinish Clearcoat Resins（2）汽车修补清漆树脂汽车修补清漆树脂Setalux 1204 XS-60low solids acrylic polyol with 3.0%OH(on non-volatiles)低固体份羟值3.0%丙烯酸good drying properties under severe conditions在苛刻条件下快干good hardness build-up 好的实干硬

28、度Setalux 1192 SS-60low solids acrylic polyol with 3.8%OH(on non-volatiles)低固体份羟值3.8%丙烯酸fast drying with good overspray take-up 厚涂时快干good adhesion 附着力好Vehicle Refinish Clearcoat Resins（3）汽车修补清漆树脂汽车修补清漆树脂Setalux 1753 SS-70medium solids acrylic polyol with 4.2%OH(on solid)中固体羟值4.2%丙烯酸fast drying 快干good

29、 hardness/flexibility 硬度和柔韧性好的平衡good appearance with high build and gloss好的丰满度和光泽外观Vehicle Refinish Clearcoat Resins（4）汽车修补清漆树脂汽车修补清漆树脂Setalux 1190 SS-61(XYL/PMA)low solids acrylic polyol with 4.5%OH(on non-volatiles)低固体份羟值4.5%丙烯酸good leveling and appearance 流平和外观好good outdoor durability 户外耐久性好Setal

30、ux 1211 BA-65medium solids acrylic polyol with 3.0%OH(on non-volatiles)中固体份羟值3.0%丙烯酸good leveling and appearance 流平和外观好very high gloss 非常高的光泽Vehicle Refinish Clearcoat Resins（5）汽车修补清漆树脂汽车修补清漆树脂Setalux 1198 SS-70medium solids acrylic polyol with 4.2%OH(on non-volatiles)中固体份羟值4.2%丙烯酸good leveling and

31、appearance 外观流平好good outdoor durability 户外耐久性好Setalux 1215 BA-68medium solids acrylic polyol with 4.5%OH(on non-volatiles)中固体份羟值4.5%丙烯酸good leveling and appearance 流平和外观好good drying properties 好的干燥性能Vehicle Refinish Clearcoat Resins（6）汽车修补清漆树脂汽车修补清漆树脂Setalux 1901 SS-75high solids acrylic polyol with

32、 5.4%OH(on non-volatiles)高固体羟值5.4%丙烯酸very good durability 户外耐久性好good flexibility柔韧性好Setalux 1903 BA-75high solids acrylic polyol with 4.5%OH(on non-volatiles)高固体羟值4.5%丙烯酸fast drying 快干good gloss 光泽好Vehicle Refinish Clearcoat Resins（7）汽车修补清漆树脂汽车修补清漆树脂Setal 1615 SS-75high solids polyester polyol with

33、4.4%OH(on non-volatiles)高固体聚酯多元醇4.4%羟值very good durability 非常好的耐久性good flexibility 柔韧性好Setal 1603high solids polyester polyol with 5.4%OH(on non-volatiles)高固体聚酯多元醇5.4%羟值very good durability非常好的耐久性good flexibility柔韧性好good hardness build-up 好的实干硬度Vehicle Refinish Clearcoat Resins（8）汽车修补清漆树脂汽车修补清漆树脂Set

34、alux XSZ 1107 SS-70medium solids acrylic polyol with 3.0%OH(on non-volatiles)中固体份羟值3.0%丙烯酸good leveling and appearance 外观流平好good chemical resistance 耐化学性好good fast drying 快干好 Setalux XSZ 1003 BA-68medium solids acrylic polyol with 4.5%OH(on non-volatiles)中固体份羟值4.2%丙烯酸good leveling and appearance 流平和

35、外观好good UV yellowing and durability 好的黄变耐老化性能Vehicle Refinish Clearcoat Resins（9）汽车修补清漆树脂汽车修补清漆树脂Setalux 57-2500medium solids acrylic polyol with 4.2%OH(on non-volatiles)中固体份丙烯酸羟值4.2%丙烯酸good gloss and DOI appearance 光泽和鲜映性好good chemical resistance“MEK rub”耐化学性好“丁酮擦拭”super fast drying and long potlif

36、e 超快干和活化期长Very good exterior durability 非常好户外耐久性Setalux 57-2500 Zero VOC Acrylic Polyol零零VOC羟基丙烯酸羟基丙烯酸 Clearcoat ready to buff in 30 minutes 快速清漆抛光 Ultra-fast hardness development 超快的硬度提升57-2500Conventional Acrylic PolyolVehicle Refinish Clearcoat Resins VOC汽车修补清漆树脂有机挥发排放汽车修补清漆树脂有机挥发排放Vehicle Refini

37、sh Clearcoat ResinsDrying time/Hardness汽车修补清漆树脂汽车修补清漆树脂 干燥干燥/硬度硬度Vehicle Refinish Clearcoat ResinsCar wash resistance汽车修补清漆树脂汽车修补清漆树脂 耐擦洗耐擦洗car wash test according PSA RNUR D24 5359 Vehicle Refinish Clearcoat ResinsUVCON:yellowing/cracking 汽车修补清漆树脂紫外照射汽车修补清漆树脂紫外照射clearcoats with UVA/HALSVehicle Refi

38、nish Clearcoat ResinsFlorida:5 year exposition 汽车修补清漆树脂汽车修补清漆树脂 福罗里达暴晒福罗里达暴晒clearcoats with UVA/HALSVehicle Refinish Clearcoat ResinsFlorida:1 year exposition汽车修补清漆树脂汽车修补清漆树脂 福罗里达暴晒福罗里达暴晒clearcoats with UVA/HALSVehicle Refinish Clearcoat ResinsStarting Point Formulations 汽车清漆树脂起始配方汽车清漆树脂起始配方 Solvent

39、borne 溶剂型溶剂型 Setalux 1152REC 96083 Setalux 1186REC 99052 Setalux 1192REC 99068 Setalux 1190REC 00051 Setalux 1198REC 02010 Setalux 1204REC 01001 Setalux 1211REC 04023 Setalux 1215REC 04037 Setalux 1753REC 99075 Setalux 1901+Setal 1615REC 99019,99023 Setalux 1903REC 03003 Setalux 1903+Setal 1603REC 0

40、3005,05013Vehicle Refinish Monocoat 汽车修补色漆汽车修补色漆Basic function 基本功能Protection against environment 保护 Aesthetics 美观Resin Requirements 树脂要求-good gloss,levelling,clarity:overall appearance 光泽，流平：综合外观-chemical resistance:no acid attack 耐化学性：酸侵蚀-weathering resistance:outdoor durability 耐候性：户外耐久性-fast dry

41、ing/hardness development:earlier handling/polishability快干/硬度：尽早的操作/打磨性-low colour:no problems in colour matching 低的颜色：不影响色差-good adhesion:intercoat adhesion 好的层间附着力Vehicle Refinish Monocoat 1K Resins Overview汽车修补色漆单组份树脂概括汽车修补色漆单组份树脂概括Solvent borne溶剂型nitrocellulose lacquers 硝基漆 :Setal 84oxidatively d

42、rying 氧化干燥 :Setal 196fast drying acrylic 快干丙烯酸 :Setalux 2117 with Setyrene 78Vehicle Refinish Monocoat 2K Resins Overview汽车修补色漆双组份树脂概括汽车修补色漆双组份树脂概括Solventborne 溶剂型Standard 标准:Setalux 1152fast drying 快干:Setalux 1204good appearance 外观:Setalux 1190，Setalux XSZ1107economy grade 实惠:Setalux 1199,Setalux 1

43、186medium solids 中固体份:Setalux 1753,Setalux 1211 high solids acrylic高固体:Setalux 1901,Setalux 1903high solids polyester高固体:Setal 1615,Setal 1603 good pigment wetting 颜料湿润性:Setal 161Super fast drying 超快干 ：Setalux 57-2500Good outside durability ：Setalux XSZ 1003Vehicle Refinish Monocoat Resins Products(

44、1)汽车修补色漆树脂概括汽车修补色漆树脂概括Setal 84short oil alkyd based on non-drying fatty acid不干脂肪酸短油醇酸good pigment wetting 颜料湿润性好good appearance 外观好good weathering resistance 耐候性好Setal 196medium oil alkyd based on air drying fatty acids气干型中油醇酸fast drying with good hardness build-up快干好的实干硬度good appearance 外观好good wea

45、thering resistance 耐候性好Vehicle Refinish Monocoat Resins Products(2)汽车修补色漆树脂产品汽车修补色漆树脂产品Setal 161medium solids polyester polyol with 3.1%OH(on NV)中固体份聚酯羟值3.1%（固体）good hardness 硬度好good flexibility 柔韧性好good outdoor durability 户外耐久性好Setalux 57-2500medium solids acrylic polyol with 4.2%OH(on NV)中固体份丙烯酸羟值

46、4.2%丙烯酸good gloss and DOI appearance 光泽和鲜映性好good chemical resistance“MEK rub”耐化学性好“丁酮擦拭”super fast drying and long potlife 超快干和活化期长Very good exterior durability 非常好户外耐久性Vehicle Refinish Monocoat Resins Products(3)汽车修补色漆树脂产品汽车修补色漆树脂产品Setalux 1199low solids acrylic polyol with 3.5%OH(on NV)fast drying

47、 with good hardness 快干和好的硬度good appearance with high gloss 外观好和光泽度高good chemical resistance 好的耐化学性Setalux 1753medium solids acrylic polyol with 4.2%OH(on non-volatiles)fast drying 快干good hardness/flexibility 好的硬度/柔韧性good appearance with high build and gloss 高丰满度光泽外观好Vehicle Refinish Monocoat Resins

48、Products(4)汽车修补色漆树脂产品汽车修补色漆树脂产品Setalux XSZ 1107 SS-70medium solids acrylic polyol with 3.0%OH(on non-volatiles)中固体份羟值3.0%丙烯酸good leveling and appearance 外观流平好good chemical resistance 耐化学性好good fast drying 快干好 Setalux XSZ 1003 BA-68medium solids acrylic polyol with 4.5%OH(on non-volatiles)中固体份羟值4.2%丙

49、烯酸good leveling and appearance 流平和外观好good UV yellowing and durability 好的黄变耐老化性能Vehicle Refinish Monocoat Resins Products(5)汽车修补色漆树脂产品汽车修补色漆树脂产品Setalux 2117thermoplastic acrylic 热塑性丙烯酸树脂very fast drying 非常快干good hardness 硬度好Setyrene 78acrylic modified alkyd 丙烯酸改性醇酸fast drying 快干good pigment wetting 好

50、的颜料湿润性Vehicle Refinish Monocoat Resins VOC汽车修补色漆树脂汽车修补色漆树脂VOCVehicle Refinish Monocoat 1 K ResinsStarting Point Formulations汽车修补色漆单组份树脂汽车修补色漆单组份树脂 Solventborne 溶剂型溶剂型nitrocellulose based硝基:Setal 84REC 00066oxidatively drying 氧化干燥:Setal 196REC 96036fast drying acrylic:Setalux 2117+Setyrene 78REC 9905