液体中激光烧蚀法制备纳米材料课件.ppt

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1、Group members:Ou Qian,Chao Zhang,Dan Jia,Yanping Su,Lulu Wen,Gangfeng Wei,Yongkui Wang,Dongfang Wang,Xiangyang Song,Wen Wang,Haiying Zheng.Nanomaterials Generated by Laser Ablation in LiquidsBasic mechanism of LAL(laser ablation in liquids)Sketch of the main stages of LALPhys.Chem.Chem.Phys.,2013,15

2、,3027-3046Basic mechanism of LALSketch of the plasma plume formed by laser ablation of a metal target.*Denotes excited and/or ionized statesPhys.Chem.Chem.Phys.,2009,11,38053821Basic mechanism of LALFeO Nanoparticles by LALAdv.Funct.Mater.2012,22,13331353Nanoparticles Derived from LAL methodMetastab

3、le structureUltra-small size distributionUnoccupied/charged surfacesEasy-functionalizationNew structures and propertiesQuantum size effectsHigh activity and reactivityLAL-inducedNPsStable and surface passivated Nanoparticles Synthesized by Chemical Routes Capped with various stable reagents to preve

4、nt aggregation or reactionA(assemble or growth)A+B=C New compounds=AB Composites Activity and Reactivity CBAAB+A+AAAAAorExamples1.LAL-based to fabricate carbon-encapsulated metal carbides2.LAL-based synthesis of ternary oxides3.LAL-based complex oxidenoble metal nanocompositespulse laseracetonetarge

5、tTantalum target1.LAL-based to fabricate carbon-encapsulated metal carbidesTaCC NPsCarbon,2013,55,108115 NbCC MoxCC Co3CCMo in ethonalNb in ethonalCo in acetoneMore products can be synthesizedthe formation process of carbon-encapsulated metal carbides2.LAL-based synthesis of ternary oxidesJ.Mater.Ch

6、em.,2012,22,1721017214Design for ternary oxides based on A+B=Cvarious ternary oxidesMorphology,structure and size can be modifiedReaction temperatureReaction timepH value3.LAL-based complex oxidenoble metal nanocompositesAdv.Mater.2013,25,20402044Brief Summary LAL-generated NMs present unique activity,beneficial for obtaining new properties and new structures LAL-generated NMs display unique reactivitycan be used as precursors for preparing new materials Laser-generated NMs show unique applicationin catalyst,biosensor etc.

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