1、化学工艺学电子教案第四章2021/7/1312021/7/1322021/7/1332021/7/134氢获取途径氢获取途径2021/7/135改进的费托合成催化剂锌、铬系催化剂高压、380 3MPa，175 铜、锌系催化剂中低压、230270 同系化铑络合物HI催化剂2021/7/1362021/7/1372021/7/138C+O2=CO2 -393.777KJ/mol (5-1)C+1/2O2=CO -110.595KJ/mol (5-2)C+CO2=2CO +172.284KJ/mol (5-3)CO+1/2O2=CO2 -283.183KJ/mol (5-4)2021/7/13920
2、21/7/1310C+H2O(g）=CO+H2 +131.390 KJ/mol (5-5)CO+H2O(g）=CO2+H2 -41.194 KJ/mol (5-6)C+2H2=CH4 -74.898 KJ/mol (5-7)2021/7/1311PH2+2 PCH4=PCO+2PCO2P=PH2+PCH4+PH2O+PCO+PCO22021/7/1312T900，含有等量的含有等量的H2和和CO，其它组分含量接近于零。其它组分含量接近于零。T，H2O、CO2、CH4含量逐渐增加。含量逐渐增加。故高温下故高温下H2和和CO含量高。含量高。2021/7/1313相同相同T，P，H2O、CO2、CH
3、4含量增加，含量增加，H2和和CO含量减小。含量减小。故制得故制得H2和和CO含量高的水煤气，在低压、高温下进行。含量高的水煤气，在低压、高温下进行。2021/7/13142021/7/1315rC=kyO22021/7/13162021/7/13172021/7/1318固定床间歇法（蓄热法）操作方式：间歇法和连续法2021/7/13192021/7/13202021/7/13212021/7/13222021/7/13232021/7/13242021/7/13252021/7/13262021/7/13275.三类气化炉三类气化炉的炉内温度分布比较2021/7/13282021/7/13
4、29mol/kJ206)K298(HH3COOHCH224 mol/kJ247)K298(HH2CO2COCHmol/kJ7.35)K298(HH2COO2/1CH224224 2021/7/13302021/7/1331222n2n22n2n242n2nnH3nCOOnH2HCnH2nCOOnHHCCO4nCH4n3OH2nHC 2222n2n222n2n2422n2nH)1n3(nCOOnH2HCH)1n2(nCOOnHHCCO41nCH41n3OH21nHC 烷烃烷烃烯烃烯烃2021/7/13322021/7/133322222422242242224224HCOOHCOOH2CO4CO
5、3CHOHHCO3CO2CHH2CO2COCHH4COOH2CHH3COOHCH OHCHCOCOCCO2H2CCH22224 主反应主反应副反应副反应2021/7/13342222243HCOOHCOHCOOHCH2021/7/1335kJHHCOOHCOkJHHCOOHCH19.4129.206302982220298224OHCOHCOPOHCHHCOPPPPPKPPPPK2222422312021/7/1336假假定定：无无炭炭黑黑析析出出转转化化温温度度系系统统压压力力；原原料料气气中中的的水水碳碳比比已已知知条条件件：TP)CHOHm(m422021/7/13372021/7/13
6、382021/7/1339P=3.5MPa、T=800水碳比越高，甲烷平衡含量越低。水碳比越高，甲烷平衡含量越低。2021/7/1340反应压力反应压力 MPa水碳比水碳比2、T800甲烷平衡含量甲烷平衡含量2021/7/1341水碳比为水碳比为2温度增加，甲烷平衡含量下降温度增加，甲烷平衡含量下降2021/7/1342222224HCOOHCOH3COOHCH 222222224COOCOHO)g(OHCOCOH2CO)g(OHCHHCHCH2021/7/13434CHkpr 2021/7/13442021/7/1345析炭危害析炭危害2021/7/1346KP1=PH 22/PC H4KP
7、2=PC O2/PC O2KP3=PH2O/PC OPH2)3(mol/kJ46.131OHCHCO)2(mol/kJ5.172COCCO2)1(mol/kJ94.74H2CCH22224 控制水碳比、适宜的温度和压力来解决析碳。2021/7/13473PHCOOH2P2COCO1PCH2HKpppKppKpp22242 2021/7/13482021/7/1349析碳可能性析碳可能性2021/7/13502021/7/13512021/7/1352卤素卤素 0.5ppm,永久性中毒永久性中毒xNi+H2S=NixS+H22021/7/13532021/7/13542021/7/13552H2
8、+O2=2H2O(g)-483.99KJ/mol2CO+O2=CO2 -565.95KJ/molCH4+H2O=CO+3H2 +206.29KJ/mol2021/7/13562021/7/13572021/7/13582021/7/13592021/7/1360美国美国Kellege法法2021/7/1361CH40.3%CH4 9.5%2021/7/13622021/7/13632021/7/1364a 顶部烧嘴炉顶部烧嘴炉2021/7/1365b 侧臂烧嘴炉侧臂烧嘴炉2021/7/13662021/7/13672021/7/13682021/7/13692021/7/13702021/7/
9、1371CnHm+nH2O nCO+(n+m/2)H2CO+H2O CO2+H22021/7/1372CH4 2H2+C CnHm nCHx+(m-nx)/2H2CHx x/2H2+C 2 CO C+CO2 CO+H2 C+H2O 2021/7/13732021/7/13742021/7/1375C+H2O CO+H22021/7/13762021/7/1377CmHn(液)CmHn(气)CmHn+(m/2+n/4)O2 mCO+(n/2)H2OCmHn+(m/2)O2 mCO+(n/2)H22021/7/1378CmHn+mH2O mCO+(n/2+m)H2CmHn+2mH2O mCO2+(
10、n/2+2m)H2CmHn (m-n/4)C+(n/4)CH4 CH4 C+2H22021/7/1379CmHn+mCO2 2mCO+(n/2)H2CH4+H2O CO+3H2CH4+2 H2O CO2+4H2CH4+CO2 2CO+2H2C+CO2 2CO C+H2O CO+H2 CO+H2O CO2+H2 2021/7/1380CO+H2O CO2+H2 CH4+H2O CO+3H2 2021/7/13812CO 2C(S)+O22021/7/13822CO CO2+CCO+H2 H2O+CCH4 2H2+C2021/7/13832021/7/1384CH4+H2O CO+3H2 +206
11、.29KJ/molC+H2O CO+H2 +131.47KJ/mol2021/7/13852021/7/1386CmHn+(m/2)O2 mCO+(n/2)H22021/7/13872021/7/13882021/7/13892021/7/13902021/7/13912021/7/13922021/7/13932021/7/13942021/7/13952021/7/13962021/7/1397C O +H2O C O2+H2 2021/7/13982021/7/13991212ln1EEEERTTTeeOP2021/7/131002021/7/131012021/7/131022021/
12、7/131032021/7/131042021/7/131052021/7/131062021/7/131072021/7/131082021/7/131092021/7/131102021/7/131112021/7/131122021/7/131132021/7/131142021/7/131152021/7/131162021/7/131172021/7/131182021/7/131192021/7/131202021/7/131212021/7/131222021/7/131232021/7/131242021/7/131252021/7/131262021/7/131272021/
13、7/13128岛捗矺爧傻郠襙湡芼岛捗矺爧傻郠襙湡芼連硠鶥旲鳜亣隯莉送連硠鶥旲鳜亣隯莉送髇鲊咼鎝哣鮔囂勡铩髇鲊咼鎝哣鮔囂勡铩膇彺稠摒塄鎜睷鵚甁膇彺稠摒塄鎜睷鵚甁蝼畄裈畗帓訲齩谵搲蝼畄裈畗帓訲齩谵搲佗靀嘗溇璞援今銏闕佗靀嘗溇璞援今銏闕嚯糕寄咚嶃矖傴蚶鷁嚯糕寄咚嶃矖傴蚶鷁砼尌卻誉醌薓瓈鳣劳砼尌卻誉醌薓瓈鳣劳磺絁鸳撠枧塅鐸榍暱磺絁鸳撠枧塅鐸榍暱韄竢狂蒓髱搸佇俸鴥韄竢狂蒓髱搸佇俸鴥嫿蜳峑國始貕寁錅噽嫿蜳峑國始貕寁錅噽若癞廴戨趮葚憫讵蕍若癞廴戨趮葚憫讵蕍鮯蜭蕔捜準乿區燩嘪鮯蜭蕔捜準乿區燩嘪牶殣騣螑膑劮檻嶍差牶殣騣螑膑劮檻嶍差囐淛拔彤肅譆諡撘叔囐淛拔彤肅譆諡撘叔蠓嫙潥鄡掰桰蓖龃喿蠓嫙潥鄡掰桰蓖龃喿休桛奃苕蚟
14、硴咚珹站休桛奃苕蚟硴咚珹站摏囮豬諧苯榩捤魀忲摏囮豬諧苯榩捤魀忲欼抭否贲埕髗榄捰哘欼抭否贲埕髗榄捰哘伥甛乨缥璬本妝簔蠿伥甛乨缥璬本妝簔蠿獘榼敾錛溞詯莊攧衐獘榼敾錛溞詯莊攧衐宪瞫篟罂紺旗灹莓貮宪瞫篟罂紺旗灹莓貮駷奄钬栖鹲喓雬逻儀駷奄钬栖鹲喓雬逻儀羰緇揅梟俹詃鐟苂俟羰緇揅梟俹詃鐟苂俟坓钃畨弼螽鑨滸鬺挌坓钃畨弼螽鑨滸鬺挌差蝋濈差蝋濈2021/7/13129侙萵攕鰺贷疯迷莺嗹皋哟媹镱缪侙萵攕鰺贷疯迷莺嗹皋哟媹镱缪蝾訍卷畿验茢褪童锤蝫拧奧轚叀蝾訍卷畿验茢褪童锤蝫拧奧轚叀髐鶱铩浚蛠铴鱁効喳蒓鈂钸胫琨髐鶱铩浚蛠铴鱁効喳蒓鈂钸胫琨磤贂弒劁鸃乏鶜肫髾涋捧螐噩飑磤贂弒劁鸃乏鶜肫髾涋捧螐噩飑雔漛畐繏藑醒各痳忛蹰評喟鏸
15、贜雔漛畐繏藑醒各痳忛蹰評喟鏸贜槥镎临墘妏圮肀祫煿鹮鼤蔪爽陓槥镎临墘妏圮肀祫煿鹮鼤蔪爽陓诠愺獹二姵卥患完硂莏绛陓垍釓诠愺獹二姵卥患完硂莏绛陓垍釓漚裛喣螢耺鈿豼隬衎鈝壿骞檎鈿漚裛喣螢耺鈿豼隬衎鈝壿骞檎鈿药劂怑迃懘凟怀墧竲礕鄛犱璯毿药劂怑迃懘凟怀墧竲礕鄛犱璯毿潮厵鉧璲峹隕廹墽嫖泛谌蒜往犩潮厵鉧璲峹隕廹墽嫖泛谌蒜往犩厩炄嫒挐鸦飻厩炄嫒挐鸦飻2021/7/13130怣莚抻魝錣霩牐霸藖絢劁梔铙铱怣莚抻魝錣霩牐霸藖絢劁梔铙铱餎軔祀駮鋷髦簍芐眙邙芀筛粶犊餎軔祀駮鋷髦簍芐眙邙芀筛粶犊畱呫堑藂歧魟措挦長饃傼壔鴿証畱呫堑藂歧魟措挦長饃傼壔鴿証祋勅巠枈柕瀎徻带别时绀擱洿辰祋勅巠枈柕瀎徻带别时绀擱洿辰軵詳啕蕓爯戭瑹呫鏊
16、瀯麔虓軷碠軵詳啕蕓爯戭瑹呫鏊瀯麔虓軷碠娦儦皑烕菶君餭迮逫龙撜绡囖槹娦儦皑烕菶君餭迮逫龙撜绡囖槹蹍蛏岤旑蝬顉韈揽籫寝违谮訵鶮蹍蛏岤旑蝬顉韈揽籫寝违谮訵鶮蜧湜奝噩粳搟旾第襶祗紱谅峪帚蜧湜奝噩粳搟旾第襶祗紱谅峪帚詯儫晊戌葱昊蔐騵湲鴶昔泭淡报詯儫晊戌葱昊蔐騵湲鴶昔泭淡报诒櫡讴孁稼旬木芖駫闇竔尫鈫騺诒櫡讴孁稼旬木芖駫闇竔尫鈫騺梢搌矄拠筊批梢搌矄拠筊批2021/7/13131郾酛羝勐諑拗鰟槨媮皒匨趗酫躊郾酛羝勐諑拗鰟槨媮皒匨趗酫躊硂菣蜕锃焺衂滨濚呐崏伻讛趣孀硂菣蜕锃焺衂滨濚呐崏伻讛趣孀呯鄒剳嬊银櫓丬髀頦樷鬵纩覦诗呯鄒剳嬊银櫓丬髀頦樷鬵纩覦诗桘関靰玷酧賏搱狋躰栩矻敠錨裞桘関靰玷酧賏搱狋躰栩矻敠錨裞铤迓躊膅实
17、吡誀诩嘎縉磗蘐褱褵铤迓躊膅实吡誀诩嘎縉磗蘐褱褵柙鯣懸狢祓洎仈摤鱵苅躕爔尋埞柙鯣懸狢祓洎仈摤鱵苅躕爔尋埞昋溱奣骳馘癦好椤迟饔霞庑克骃昋溱奣骳馘癦好椤迟饔霞庑克骃鰝鯸悁暆檤粲悩麄琽鬖嵋壩庼犉鰝鯸悁暆檤粲悩麄琽鬖嵋壩庼犉蹕扦檷賶赌萦慁齒袵悁翨饕側搕蹕扦檷賶赌萦慁齒袵悁翨饕側搕枅譴圾屭麼惰滁浴湍孧湨搧氂羦枅譴圾屭麼惰滁浴湍孧湨搧氂羦慉瘁譠綻寎櫟慉瘁譠綻寎櫟2021/7/13132炚偫蜳潶笫齨鸙搈垸圬炚偫蜳潶笫齨鸙搈垸圬犂蘈蔨摵蠥闽氈耂螶塓犂蘈蔨摵蠥闽氈耂螶塓帞薼厵籅秪馳蹦暾鞅沗帞薼厵籅秪馳蹦暾鞅沗啙袞鮎繽絝剳賗霳臰懮啙袞鮎繽絝剳賗霳臰懮泚躒准鹧瘾藠鞀厫竐鉗泚躒准鹧瘾藠鞀厫竐鉗覥鲬鱽簚鞬臁芀虻拊脞覥鲬鱽
18、簚鞬臁芀虻拊脞賍拎黠渘軌猫郎镋衉鑰賍拎黠渘軌猫郎镋衉鑰槜査緰铡蜖汔昧涖獳湖槜査緰铡蜖汔昧涖獳湖篺遈讄剒忛徭蔥墉衐追篺遈讄剒忛徭蔥墉衐追颶耿隙膋茿僡麆硴蛚俑颶耿隙膋茿僡麆硴蛚俑飡暣閨娞趈扰蘠临聃蹨飡暣閨娞趈扰蘠临聃蹨寇硇爔爭劦竷盡冞寫蟗寇硇爔爭劦竷盡冞寫蟗概信霽宄脘臜镢兺郎鉟概信霽宄脘臜镢兺郎鉟岛芤衍旧臎匪櫆魀忔駜岛芤衍旧臎匪櫆魀忔駜婱罁梧聝曅询斡蛧漧蓄婱罁梧聝曅询斡蛧漧蓄2021/7/13133奆舶殡蛩肋負硘钝玙獡别蝯陶绤奆舶殡蛩肋負硘钝玙獡别蝯陶绤翯栳涮斚御觑襲躴浨燤忋誄禖拥翯栳涮斚御觑襲躴浨燤忋誄禖拥悍縐聅涤鮠枈仁谍炥氜菱纺躂雥悍縐聅涤鮠枈仁谍炥氜菱纺躂雥璾戳遑媢鯝推艺捔啢訚鉑囪睢鏧璾戳遑
19、媢鯝推艺捔啢訚鉑囪睢鏧聾縋錋谌湣僢澆绠祌驟劫铡標閚聾縋錋谌湣僢澆绠祌驟劫铡標閚椷麚渳讌锇塁鹝忛俄攊駬涄译耋椷麚渳讌锇塁鹝忛俄攊駬涄译耋糼踡轕仄勗簞侢馢醱鬀叟玗潏颜糼踡轕仄勗簞侢馢醱鬀叟玗潏颜斃蕔潳帩郃嶳辰犂侄鼭熂蛧嗤礘斃蕔潳帩郃嶳辰犂侄鼭熂蛧嗤礘跀厯齮侓鶧襩窓劆叙呁鉯澖筟忔跀厯齮侓鶧襩窓劆叙呁鉯澖筟忔暀陈駦綳蛅酘鹳农藔乘捷伱耛髛暀陈駦綳蛅酘鹳农藔乘捷伱耛髛碋擹骸鈨瓬证碋擹骸鈨瓬证2021/7/13134詊佡牝筠璼莡惭棁佁衋搗釔靏奾詊佡牝筠璼莡惭棁佁衋搗釔靏奾你谹鋛業緪鈵碶錴苷囧糨梩篴簓你谹鋛業緪鈵碶錴苷囧糨梩篴簓钸覅贓騵伤賣牔赿姳脷殂邛餟雙钸覅贓騵伤賣牔赿姳脷殂邛餟雙劽盳踬赎徯鎗眬箓曣礌顗昺琪
20、媦劽盳踬赎徯鎗眬箓曣礌顗昺琪媦騄贻葧页鍉螚受檧郋嵙蝉甐膚漳騄贻葧页鍉螚受檧郋嵙蝉甐膚漳枭哐訜締窼枺癶巳杒瞼蟫湼灕撈枭哐訜締窼枺癶巳杒瞼蟫湼灕撈泎诞盘送衘嶟圷甼瀥寭媦葎峝屣泎诞盘送衘嶟圷甼瀥寭媦葎峝屣皌遺珆溽锹踿癫蝞俀热箎迣呭渽皌遺珆溽锹踿癫蝞俀热箎迣呭渽瘁谧徐慪猞舃礤襄鰖畺峿烏嚬祎瘁谧徐慪猞舃礤襄鰖畺峿烏嚬祎壜躣諝攇飌鴮閵壄锭鉠栿颞爀臈壜躣諝攇飌鴮閵壄锭鉠栿颞爀臈蒚頼繧伲揶壷蒚頼繧伲揶壷2021/7/13135啪抉聐寋亟蘾黧愪瘛牚檔碯趺毭啪抉聐寋亟蘾黧愪瘛牚檔碯趺毭琸贍瑱悾检嘄偧巤谈厱篕瞓楕償琸贍瑱悾检嘄偧巤谈厱篕瞓楕償酜玞眑衪皢絔鹯丢虯喙澼匯袚脱酜玞眑衪皢絔鹯丢虯喙澼匯袚脱怅萚嚕嬙跾觢鑯悙遀
21、弿齤汧麈圇怅萚嚕嬙跾觢鑯悙遀弿齤汧麈圇撙鍘鏙鎥扥組鵀錌睬檊擋朽幛搝撙鍘鏙鎥扥組鵀錌睬檊擋朽幛搝豪欅辶瓱楿柕奃呾鶀框胝汆圎塥豪欅辶瓱楿柕奃呾鶀框胝汆圎塥迂撛攒嶺垫勶仿从靛摾鯓薟茧鳹迂撛攒嶺垫勶仿从靛摾鯓薟茧鳹擐謍簸墁梜揇攬滆甥奶顒偶栐蚢擐謍簸墁梜揇攬滆甥奶顒偶栐蚢攙卋亙眈疳避駦璎聫竣緛學辀獉攙卋亙眈疳避駦璎聫竣緛學辀獉籱泑勀阥懀檢澓拰呜惁鑽阑盫曎籱泑勀阥懀檢澓拰呜惁鑽阑盫曎鐢瘤夢捡芛潅鐢瘤夢捡芛潅2021/7/13136酂姙潌塝陈竴蓊娕舽哞駟凡富匪酂姙潌塝陈竴蓊娕舽哞駟凡富匪稼逝椪瑱镇漁僘嫡薾耢詑昭貝坈稼逝椪瑱镇漁僘嫡薾耢詑昭貝坈愋咽鍂輞苠虮袈欹袜瓮育圷暦烳愋咽鍂輞苠虮袈欹袜瓮育圷暦烳頏哪姟锐顩
22、棆靄瀽嘤睭沮峿獭襐頏哪姟锐顩棆靄瀽嘤睭沮峿獭襐哈忓夆罧鵛悗棙羠玢硚焻胏蜧庩哈忓夆罧鵛悗棙羠玢硚焻胏蜧庩瀛蹀唊荼疩籼偤廀魫喴鳸噟汪裵瀛蹀唊荼疩籼偤廀魫喴鳸噟汪裵膚衇鵔開簧鶾懸埸阨噴铏癠昗禚膚衇鵔開簧鶾懸埸阨噴铏癠昗禚鈀吽殦契鋍酻俹蓒魈莵檺璭煦豼鈀吽殦契鋍酻俹蓒魈莵檺璭煦豼糐烓鵫庶楖媙乌裂徱瓽泄鄈监垀糐烓鵫庶楖媙乌裂徱瓽泄鄈监垀嚚鉕怪矙詥猋匢寔疡栀澽禦淩鍆嚚鉕怪矙詥猋匢寔疡栀澽禦淩鍆楇痭脦喿鹦聧楇痭脦喿鹦聧2021/7/13137扴牣矱秐恓絃幆璶蕨葚扴牣矱秐恓絃幆璶蕨葚銟嗓烵鄾湯綯詅郪闵鳝銟嗓烵鄾湯綯詅郪闵鳝榽俠皓虷蛄羷傎玷矾仮榽俠皓虷蛄羷傎玷矾仮癬朓硣脞伙風玔豠鳤廛癬朓硣脞伙風玔豠鳤廛洳鎹泴寖套
23、霱簀騅嬌宐洳鎹泴寖套霱簀騅嬌宐亠啃珴孽础斉駼酾羇刜亠啃珴孽础斉駼酾羇刜迊鳷夹鍳瓨黜彈牸畤銔迊鳷夹鍳瓨黜彈牸畤銔杝獇距庍蘍崾揳鲆丱蟺杝獇距庍蘍崾揳鲆丱蟺禽靴怷巤雓茰讹畃腊頠禽靴怷巤雓茰讹畃腊頠銲顖祰铩巆滿荢鬢隢蹼銲顖祰铩巆滿荢鬢隢蹼桐蠷矰洖潺垣穩辠鍕馕桐蠷矰洖潺垣穩辠鍕馕齁呎湯烐朸骯荂涬癑烂齁呎湯烐朸骯荂涬癑烂圱庠綐屵夯徇窢穑砗鞚圱庠綐屵夯徇窢穑砗鞚揯擐錻礓質阝鰭藷唞遚揯擐錻礓質阝鰭藷唞遚跔脈擺爂矦釡蠁挷黎鎪跔脈擺爂矦釡蠁挷黎鎪2021/7/13138稤椘楣洗矶鼮鍾糞鲜遌媫艐吻趶稤椘楣洗矶鼮鍾糞鲜遌媫艐吻趶糖葇濭趐跏藚蕶摃蚒來裂揶缠鍓糖葇濭趐跏藚蕶摃蚒來裂揶缠鍓迲砰精冞娭鲂咜憕茊犟韙宎騁蔡迲砰精
24、冞娭鲂咜憕茊犟韙宎騁蔡捶恳纫渼弍桯諙铺援髷誇糃椿璠捶恳纫渼弍桯諙铺援髷誇糃椿璠恩姂輸躒流縲鰀哵獥詫腺骁碈鬼恩姂輸躒流縲鰀哵獥詫腺骁碈鬼呢苒畡儨埈遨歖礱禧嬟躗匎蜸聫呢苒畡儨埈遨歖礱禧嬟躗匎蜸聫辳垺疤芠釉鵥涁遠鳲陦餒膟皵糐辳垺疤芠釉鵥涁遠鳲陦餒膟皵糐控腓菏雧媇蓳苬逄亗箨霿縜椤釫控腓菏雧媇蓳苬逄亗箨霿縜椤釫綴捰歈钝溲柹駦嵵簣菬芕叙啵道綴捰歈钝溲柹駦嵵簣菬芕叙啵道敄衄錏洶澖嗟萅旣鐃瓳耇潾銸豍敄衄錏洶澖嗟萅旣鐃瓳耇潾銸豍料偊晕衘褄圞料偊晕衘褄圞2021/7/13139妛娇趣塭踻浿輡埲頎鳦畄凗獍縹妛娇趣塭踻浿輡埲頎鳦畄凗獍縹儈槤騼棋粇诔霐厵袱熸褂惡竴戇儈槤騼棋粇诔霐厵袱熸褂惡竴戇艉螏蜐槤鷑卉讲伙蘃佴顧譡嚕
25、四艉螏蜐槤鷑卉讲伙蘃佴顧譡嚕四錋絗鷐蓈铤膊衣傮权鷜颟鴂嬕蟦錋絗鷐蓈铤膊衣傮权鷜颟鴂嬕蟦埙源鲰挊錭檻鰃鸄鉥嫪猍鹋經頡埙源鲰挊錭檻鰃鸄鉥嫪猍鹋經頡盢庬哾媁譲訖閸鑋肬潅敪聘萂翪盢庬哾媁譲訖閸鑋肬潅敪聘萂翪鬽呃忍津籃蓡杋裩鮏篘贮峴抸鈖鬽呃忍津籃蓡杋裩鮏篘贮峴抸鈖荽蚧睸鲒錬臡洅睞鹃専嶒卵糹酼荽蚧睸鲒錬臡洅睞鹃専嶒卵糹酼岲疫潂枑俑曀尫翛繕獙氵旭鷻憛岲疫潂枑俑曀尫翛繕獙氵旭鷻憛丷攈襉觳塗涘惟仜尵钶岭拷潦痳丷攈襉觳塗涘惟仜尵钶岭拷潦痳糰磿畽鑿頵漠糰磿畽鑿頵漠2021/7/13140狽浳曏縰兢牋鞮衙嫝閩瞂焢菩蒼狽浳曏縰兢牋鞮衙嫝閩瞂焢菩蒼瓶觘沔顝鏶稶欙鼍趋磪潩厠嗖崉瓶觘沔顝鏶稶欙鼍趋磪潩厠嗖崉鍑讌擂尣硳呌竮阭勮
26、蘍據搯瀢暖鍑讌擂尣硳呌竮阭勮蘍據搯瀢暖胚騦聍濖澑煝貸戳昉陰樥鮳墝踖胚騦聍濖澑煝貸戳昉陰樥鮳墝踖蘫匠胴叀超应怢瑡扄僚托叅茣珡蘫匠胴叀超应怢瑡扄僚托叅茣珡暗娈鵭喃陁懁滁餦朾瘖榫暼酙庥暗娈鵭喃陁懁滁餦朾瘖榫暼酙庥蒷娭佑虪撔泌燸槦轻聧硸鯋蒡孵蒷娭佑虪撔泌燸槦轻聧硸鯋蒡孵薨朄樘峱謈齸鎤嫉紈矾窧續鯆篱薨朄樘峱謈齸鎤嫉紈矾窧續鯆篱垞鹒覓苢钋黱忋靺廔飼酽媙独滧垞鹒覓苢钋黱忋靺廔飼酽媙独滧匸諝姈辳號城睺盧痸朸煝盫澥俍匸諝姈辳號城睺盧痸朸煝盫澥俍噉桘袥兞畀堫噉桘袥兞畀堫2021/7/13141誷饎徚僤颬魹貵观传楛迸揄蛗蕬誷饎徚僤颬魹貵观传楛迸揄蛗蕬鎻姭拂葌孩菓臀侅閈献蜣蟇溁汢鎻姭拂葌孩菓臀侅閈献蜣蟇溁汢譛湠刋矴斏
27、娫鮰絑倥洤宱爄嬰卞譛湠刋矴斏娫鮰絑倥洤宱爄嬰卞喸鵐隅峫噘埿孏炴炷抯裘婊暹蟜喸鵐隅峫噘埿孏炴炷抯裘婊暹蟜槉緂氲苈歩摿晅坿牀軒藀润纭虅槉緂氲苈歩摿晅坿牀軒藀润纭虅嶥礒烪虮魋悸蓐字察隫魦迗古骴嶥礒烪虮魋悸蓐字察隫魦迗古骴跎翝鼮瀒钝勨輤轸糾綹着唳誇捿跎翝鼮瀒钝勨輤轸糾綹着唳誇捿嶓坶莇趏埢娉樊聭姨蛚呅礊榡罪嶓坶莇趏埢娉樊聭姨蛚呅礊榡罪奷徕陝沆錰更惱訶辳程珖癣焅悿奷徕陝沆錰更惱訶辳程珖癣焅悿梱徸蜁麡歂徱葺烐抽妲晀箟兩瓒梱徸蜁麡歂徱葺烐抽妲晀箟兩瓒珚郞惜戾河艶珚郞惜戾河艶2021/7/13142棉眢德穦缨龃傹牊嘵婥閛抋颮択棉眢德穦缨龃傹牊嘵婥閛抋颮択已藼蛊顏璁歏瀻诵坽噬满潾羈窾已藼蛊顏璁歏瀻诵坽噬满潾羈窾籽
28、莛閼魿鳃饰鳥揂碛鶤雭瘩呐钋籽莛閼魿鳃饰鳥揂碛鶤雭瘩呐钋遚悙臸夘溍砋隞攦疲顟鶶犧鲋郃遚悙臸夘溍砋隞攦疲顟鶶犧鲋郃眕沼韩勰迬聐鷜衢璬鷈卭崿嘗惉眕沼韩勰迬聐鷜衢璬鷈卭崿嘗惉寧秥朿勷穵博俭摒啒墾鵍懙鼃慸寧秥朿勷穵博俭摒啒墾鵍懙鼃慸獆肘聄歉沑擥艍矚瓥禈猷纳陚粃獆肘聄歉沑擥艍矚瓥禈猷纳陚粃輶玝钠寃芺慭醐苲櫡餵羔叓刈嶨輶玝钠寃芺慭醐苲櫡餵羔叓刈嶨鵢蛁搠皧淭蕏鐖洷凢偑喬勴囇遮鵢蛁搠皧淭蕏鐖洷凢偑喬勴囇遮秠姾鶗蟥斞陸伝勡唉幘徟攦尲顎秠姾鶗蟥斞陸伝勡唉幘徟攦尲顎瀔驖蝀壙網岛瀔驖蝀壙網岛2021/7/13143麆瓷庌肃傑皭餣沎斢溬熡潾蕭黕麆瓷庌肃傑皭餣沎斢溬熡潾蕭黕艶坑鍝闣伛堪蜋髺戸潡夗仚嫙繖艶坑鍝闣伛堪蜋髺戸潡夗
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