1、- ?liiE% _ _ tt- ( .dtJ:.li7i:3t) *lafflf!f rMm 2020 frfiJffi9=l*mm=rxmtit !14 tm tJ igiit #lJ?H I ( :lztlli) lPffi Il ( 4:lztlm) Wl=fflS:fr o $fl I 1 5 JJt, f!;J1-J ,m, ffi n 5 14 JJr. mlP:Wl=ms:fr 0 lJRlmiM-150 :fr;jl. t1l:fr 300 :fr 0 iiJftJIUIJA9fflXtl“ffiTJJc:ll:H -1 B -11 C -12 N -14 O -16 Br
2、-80 S:a$I.i: 1. Ulltr .1:*,ffl o. 5 ?i*ffl?1J/lli,lli-f:?A9il!tn 13 BA91liiE % ,tt o 1:iJU-f:? _tJL!it19UA9“ ?liiE% ,tt“ .!i1:*A?liiE % ,1tJ!:a-!co 2. ffi I 4ij!JM:ilim, ffl 2B fflteIE-f:? _tx,j“ ,m A9f,j%-, ltil“i/.J .m1t.:Pm .-N:JtBf,j%o ffi Il 1mffl 0. 5 ?i*-?;Jto 1. r1U:c-rffilllt19lii!, ffiA9 A
3、. ffi-A9fflnltnlt:fr J!IHi El lPfHIJ B. fiiJ tJ9 ffilll_t iiJ ff ?ffl fiiJ A9M El J( C. % 1H. t19 -ft*l!ffilllt19mttt D. -iJUJU m ffi-ft*l!ffilll ffif 3:f* 2. :1cif$1ulPWitJ9 T2 imffif*ft:kfiffffiBi, r11Jli;i!iEfft tJ9J! A. “Jffl 14N icBi*1-1-J14N fi:$:Mtt e. -t miM-raJ M * -ft 32 P t,ji.cfflt mti.t
4、,J,fflffl !kit ffii!E* M:fr.JJU J.!I! i!E* ffi llUI , ? lit 1rft :ltffl fii.1.Jt:JE tJ9 41H4= r fflH-t 1tJ:1: l!.lifM“ raJ 1t:!m m FJr or ;rJ :fr frffi tJ9 Ji! A. 00 1 1-JtkflJ.!1! ,2 1-Ji*3flJ.!1! 2 1 C. Bifil!ijffl;ffl1tA9fFffl z, B. BiiiE l!lMA9-001tA -ttlJ!ittitt D. Bil!l:liktfttJ9-$it#i-ri!E*3t
5、 m 1 JJr 4. :!zll!lft!.ffi:tt(I(JWJl!ittrffii ,a,b ffiJftlJ?lt-uzt.(o r?IJ5HJriET!fD(I(J A. *JftlJ?l:ltt, ft!.ffi:ttfflHf(I(Jft!.,firfit.-ft!.-UZ B. a 3!:JIJ.ilJftlJil:,tiflt.!f.fflift:i!ttin:fpft!.,fir 5. MflfflM,Et:mfl A 1* .Qt(I(J !.It oiffA!Jt tf t.Ui i:r 7 :;kt 1-1t MP -itt (I( .ffi#tl:Wffla-ft
6、i(-ft;n:(I(J-ftWt*S(I(Ja-ftffion*(I(J -iEtf-or-(I(J A. ntmfil#ti:Wfliliifl e. i:r (I(Ja1t-r EJ * c. MftUt$ mm!Pl i:rr Ji!jgiil D. -(I(JU1*r:fiiJ-ft(I(JftU: 6 . .%ffl 15N ic!bM.!i1.Cxttf*) fffffiJffil DNA .tlJjtffi-:rx5tmMJffil.f*fflfiiJ C. 5tjIJ:x,tlJjt5t;n:(I(Jl!Y-iffiTl.l Q N C. N,Q 7tj.!:j Z .Qtt
7、*(I(J;,j(ffi.ffl.-tt D. R, Q ,Z (I(J :Al jtfj fft-ft (I(J ;,j( t fiij Wffl:!f.JiliiI -.-.- - l 1. igj.1 1-t:tm I Cl ,IC13 A igj.iji:ffli;J.alff-B ) $1Jltit:it I Clo B :I Cl (l(J R.-127. 2C , ,#_.J 97. 4C .:,Jcftt=:= H+ + HA - -6 -8 B. Ka (HA-) (l(Jfi:iUtffll.l:lt* a c(A2-) c(HA-) = . ff:* s ,1,m, ,1
8、,a: 6 o-e,1,mttt:1:1 im1-J1cf:i, gp,; 14 -1s 11.R :ff-Ji -*,ffi19 -2I C:fifJi-*offllft6,i!ft3, :fiffflf4 0 o 14. m* JJ m rBJ. atfi*. :tE-?Xffit!:1b a, _ B:Q)25t,K.P(CaCO3) = 8.7 x 10-9 K,p(CaSO4) = 2.5 x 10-5; BeOH)2 AlOH)3 ti./9tfflw.(o lfil r Jtl fiiJ IE : ( 1) “t,311f,“ ffJt./ll./t 1600t ,;M;i:p
9、20% ff9 Al2O3 _ o . (2) t.f1ff9.Jlt:fr CaSO4, _ o (3) 1JnAIUfl-t.f.* pH 8 - 9,“ m“ lf;j“fC1:_tfJtJt!IW.1i: _ , _ , _ o ( 4) “m“ Jatllt11JnAJEitit$1:1tMfffjilj pH :iltfi“ fx“, JG-?!( 1tffl.tc ifli * 1f - fl ffJ ii- Pin.). ffJ fil ?f 11f. , AJ Jfl ft J(II. t:!tlA BzOJ rn.tttaE,.a. All wa tta EJtlmol1
10、4HUllllll. I r +o. 1 +n. r +H, Ag, Ailt“D, H- -OOH 1 2 3 H-Ag,-HH201H-Ag.-H Agi-A- :ta:-BJ:) tl9 ( ffl -ft) , PI V,( t3tj;JIJ.f !f!f.6 ir Jvt -:M(r: H202 llliiiiltffll-tlc ( NH4 )2S20a tl9 Jn:JJl!U OOFJr o ISff fll.t:Mc tl91i! -f- _ , M fJk tl9 fllffaJ1t tUr: c(Ri(h) (mgL-1) 10000.0 8000.0 4000.0 20
11、00.0 1000.0 ;fia-j fal(s) 0 7 23 39 55 Q) c(H202) = 8000.0 mg L-1 IJ;f ,v = _ mg L-1 s-1; c( H202) 5000. 0 mg L-t Ht ,tffffftlaJ-So 29. ( 11 ,r) J16-%1il*J Jfl-$ ffiJ16-% -$ 1(! )I Pf-“ffif 1i( fi Z ft , 1i( # *J Jfl -$ a9 ffi fJF Z-o#WFAiii1:ffi1llliJ1l7(ffiMJ1tir-$zumol/(gs), N No 1.31 0.73 13.2 5
12、8 42 10.07 N1so 3.34 1.15 20.8 41 59 6.22 N360 3.37 l.l5 20.6 38 62 6.11 ffil1f: ( 1 ) :i:Hi lfl l!i( pt If! eJ . 1lt JIHlriBrtJ _ ; ltJGiiil.$1:fJ i:,.Um:ii1!i!I .XE -*.XEil:fl _ o ( 4) :kfieJnf4“f rt!J1aWjpt Jt:il:*iiil.$1-J 20. 8 CO2umoV ( m2 s) ,ti ii:iiil!:- iJB _XE llll f!J * ltJGiiil $ eJ :il
13、:flltE rffiffr:p _ o ( 3 ) tEtt1:. eJ fF Jfi“f , ffil ffi r: 1:. m tt o Zffl lt , 1f tt 1:. ffi eJ 1:. !Im #ii rt -,t -*titflf eJ lffi.ttm 1z;1 , f!J EB 1tliiirfflmt eJ #ff !JJll nnf , ffi 1z;1 _ o 31. ( 10 % ) ffilt GC) nilrlf _tlllt ,A1f!tllilitJfFJij ,raffJxl.Mtt:c11 ( RA,-#tttt 1Jtttm) eJ!imz-,
14、“F00:1-J GC %We!llt = i 1 L. j CRH -1-k A(“ffi -j If J:JJlJl!li f-lJl/lii./GC) ( 1) Af*l*J GC $il:ili:fJe.IJ;j“ ,GC “f .Ii!iif*ffi!ffi.Mt_te _ .ii, If _tlllteJ GC %Wit ,f!lt1*ffi.XEo#iJaJ“il:1f5:tP4 _ o (2) RA ,i,K:wJ,f!Jij GC,lf_tlllt%W:Wffi ,lz;JltffltEraff:iifi If! fiij * t: _ , ll: If _tllltt.m
15、O ( 3 ) A f*eJ-Jl fflU :% ra f*JUMf*M El 7m ili , tr lka.tffi .!JIU -JHJl fflt!IW-tl!AJ“t .-m-# El ;w O ffijgJijeJffiJJl!x.jfitJlffll!IWili 32. ( 10 ?t) 1Ufi:1Hiff lMl%*fn*%* ,-;ffilfff $-;ffi!f fU-;ffilf, ?tJJtl Iii 1;!;) W /w ,Sis !t11itJ o;!it/JffljaJfi tal!1t ff9 -;ffi)f IMJ %*ffitlc ta1!1t ffJ
16、!)i-;ffilf *%*ffitlc3t, FI 1g!)i-;ffi!flMl%*;NJfittM* !Vff -! itl!l-=fJ.(1*) 107 103 105 105 fftUJ(l,ffl 1).-M 1).-1tff j:R j(:Rff 11%:1: -1,;m:1: IIM:I: -!,;%* fftti.(1*) 22 83 85 20 itlfilff: ( 1) -;ffi!f lMJ%*JR*lJJ F1 ffJffilffi!JtJJtl1g _ o (2) 1 1tl*r!t11itJi!thii*%fJJMffilaJil:ilffi lilffl1t$
17、?iffiJ)ijJn:ffilo (3) Z. IRJffl2 ffl.ili“!t11itJi!thii*%fJJ-;ffi!fffilaJil:ilffi Ebffl1t“, iEfD?itIYlJ.IEb 0 ( =) -: 3t 45 0 -JA 2 i!tmJl.11,2 )if.tli,2 i!tmlli:p.f-1=o:fal , muJiJffia(J-11;.+ o 33. !fwJ.1 - 3 -3 (15 ?-) ( 1) ( 5 ?-) -fil:aJJ.1:ffl9.f*i*ffl:Hl*JJA a Jf-Jm .JJJ ab,bc,cd,da ll9-1:r:1:
18、lfil JIJfJJ-Jm, T - V 00:!lllOO .91 ab 31l-fi-=f V$111,cd 1!Z-fi-=f T$111,da a9g*:r1Jn:, o,rJtl1tl*riEfDaJ. _ (iEfDffifij%oMl-iffl.2?t,M2-1f4?t, Xq“ 3 -ilf 5 J1“ o ffl 1 -iffl 3 J1“, :ffl:-flffl.?-1g O J1“) T A. a -b M, 9“.i*:Mcili aJm:il:-=f5WM9“.f*ii:ff9JJJ _/1 B. b -c M, 9“. f*?t-r aJ1!Z-;b1vJ, L
19、_J C. C -d M, 9“.i*:Mcili aJm:il:-=f9“.-f*l*Jiff9Y:il: b -a d _.,. D. d-+au,9.-f*,ffij5t o-v E. =Hltiurff;jfitJl*JltiurttrnJHJt9“.-f*?t-rmaJrx1t,b ltd aJY (2) (lo ?t) :!lllOO, w;j1Jt$Jff Jfiflj$?-9.-f*J.l1g L = 7cmo7.Ktllfi I if:2i:,ffl*J ffJffif,ffi31Z-,7(fi II ff9*J.lh = 3cmoJ!.*9“,ffip0 = 77cmHg,
20、9,-f*a,bmJ.l1gt1 = 27“Co3!.19tHI J.l1t .111t1PJr3;tJff .ft7.ktt II ff9tooJJtt I iE - hL:f b ttt II ii: ff l*J aJt.llt IJ;j 9. -f* a aJ * J.l ; a (ii) 1g T il:9“. f* a JJJJn:*ll, JjltlIJ.lmE1t1g$j;-? 34. !fmlll - 3 -4 ( 15 :fr) ( 1 ) ( 5 :fr) ;!it1J,ffi.ffl“ ffitti!“ tj!PJl-fiJtJit t19 M $. , :tm 00
21、B fUE:!lf AM:n riiJ Ao it Jltffif aa ff9,tJfl1, a,ffi“TWjft*# P1 fJl P2 ,1,2,3,4 :frjj1Jlm*“1ro ( i) ii: bb ffltlt, Mft*# P3 fJl P4 PJfIffiiE _ _t ( :11 “1“ ,“2“ ,“3“ “4“); ( ii) -9“nru iliAMB iliM,A9ii, #;iiJtJit Wffif aa a9,tJfl1, ,8,j!IJJtitagM.$. n = _ _ ( iii) *WiiliitJitM:iiIW aa ,bb .1J,f,#ft
22、fil OA O :nriiJ-T-8Nmrr-.-M$.A9-#f b- _ ( :11“ ffi*“,“ “ “ ffi1j,“) o (2) (10:fr) Ef:l,Z:.Wil?1Jffii,lff1tiElliJ-:fr-Jllt9=1:frjjljtlxiEriiJ 1 2 3 4 fJ!fftriiJffi.iE t = o IJittlM11JA9$:friltm:tmm, Ef:lit:!lfffiiJllltB M( 1. o,o), z:. lt:!lfffii(JJlltB N(2. 0,0) 0BZ:.tf9fflJWJ Tz. = 0. 4s,: (i) Jllt
23、BP(l.6,0) Jfag!Jij“Jt0; (ii) JlltB Q(2. 4,0) A9m8 r = + 20cm a91JitJ ta y/cm If! z. 10 -Q -10 - 35. -it - 3: !fmllltttlllt ( 15 :fr) ifflkJt-itit,ifmlfflrfIti,#:fSl-io ( 1) fkikifflittt#:fSI-, iltf*1-J“ lit“ ofktf9ffl-it! rtfWj!,.;1-J 4f46s2 ,9!tlfkffi rA9*nltXtit! rfi _ 1-o (2) tl:-itiff(BF3) 71iJ1
24、titf91t!l.-ff1t1flJaBF3 -Jtr(JJi“titt“ “Ft! ft“), BF3 9“ B - F rt BF4 -9“ B - F tf9flt*,2;1. _ o (3) Z:.iff( B2H6) JijfF:JfJlff9il16* #:fSI-Z-a Q) B2H6 A9:frr:tmOOFJr ,;lt9“ B ffir ff91t1Jj!,.;1g _ o H3NBH3 tf9ffixt:frrlllt B2H6 ffi *,f!l H3NBH3 ff9Bt;Jl rt B2H6 il16#J $ ,Jlz;J _ o lliJ-fflJWJ9“ .-.
25、it!:fr-r B,N ZfsJA95G- _ #a ( 4) Mllft1tA9:k#:fSl-aOO( a) -#xlS!Hlj!,.;A9iffft.9!tlififfftr % _ ,OO(h) iffllf!lidlrf-*9“1mr( * B,0,H .=#5G.) ff9. i.ffa f-*9“* ff91t-o A. rflt B. tittflt C. tittflt D. lft!mflt E. - o-0 -B Ca) . (b) (C) (5) 1:,JtMIJ( BN) ;J!iffl-.iJM-.if7!B9ffif,j*40Jt*#g51i:IXJtl.:fi
26、ffl!, ,JlJ:100 C m.JJ!U B B9ffc-j fflff JJ:IHtl: B9 M !ff fb!J 4k-lf B9 it Jit:tm r : ru-C=CP, 63%lbS04 ,._,u:t I l.t,: (! CH3 OS020H CfuCCH1 mo. I Clb OH Cl cuJ.CH Hl. CfuCCfu N,. .ll3r I CH3 Cfu A B C D CN Clli Cfh9CH3 ff. Csll1o0.1 s CJI90Cl c.HsO lti:l!it c9cooCJis CH3 Cffi E F O H I r?U liiJ mi
27、 : o A B9 - *m-atr rt:) .CD . B9l! _ , _ a (2) lf1 l.f(J_ocJ.iiijJfflj.; _ o (3) D q:ijgl?lB9;l! _ a ( 4) G B9:#gfnlA _ a (5) 1tit W 5 H ifR.l*,5trA C10H1202,nWJErlt,1tit W B9fR.!Jt#g -f*1f _ ,lf1Jtq=,5ffl*l.f(JB9:#gfnlj:. _ o a. *_r_1fM1-llitt b. :i8 FeCl3 ftrilJii c. AJ1:.t1Hl,J(fllitJ-7J-A f*A )i
28、HJsl :Jg:Jt:ff 7-E iidtf:r tfl5:1Hlnlt.iJl/i!lm lat _ o 38. !=.!Im -:lzffli:p,l:mliJattltfJ,t ,;:. .Om :ff ffi, ffl 1B 1t la -J;:. .Om :ff ffi m tE 1s“ - lfflf*mi:p, 1t* mm w l:Jl, J1J1s-_ !fl f*m 1=P , m -IJ,t leJ la , X;J-l:t Mf+m _t ffi1t a9 .fr ;ffi , tj ttl ffl -11; a (4) 2 ffllt,Jiu 1 buf:lt _ o
