1、最新一代聚丙烯透明剂最新一代聚丙烯透明剂谢春平博士，美利肯化工谢春平博士，美利肯化工 2内容简介内容简介 OutlineMilladMillad 3988i, Millad NX8000 3988i, Millad NX8000产品概述产品概述 Product SummaryMillad NX8000Millad NX8000介绍介绍 What is Millad NX8000?Millad NX8000Millad NX8000个例经济分析个例经济分析 Millad NX8000 Commercial Case Study总结总结 Conclusion 3十多年来十多年来，MilladMil
2、lad 3988 3988一直是透明聚丙烯市场的百尺竿头一直是透明聚丙烯市场的百尺竿头Millad 3988,the Industry Benchmark for Clear PolypropyleneMillad NX8000 Millad NX8000 更进一步更进一步Millad NX8000 is for the Ultimate in Clear PolypropyleneMilladMillad NX8000 NX8000 的产品定位的产品定位position in the market MilladMillad NX8000 NX8000 是透明聚丙烯领域的重大突破。其所能达到的
3、透是透明聚丙烯领域的重大突破。其所能达到的透明度增加了许多商机。明度增加了许多商机。Millad NX8000 gives a new clarity standard for cPP, a breakthrough in PP transparency, permitting attractive opportunities in market value growth through the development of new clear resins 通过取代别的透明塑料来加速聚丙烯的增长通过取代别的透明塑料来加速聚丙烯的增长Accelerating PP growth through
4、 material replacement of clear polymers 在已存在的应用通过提高顾客对更为透明产品的兴趣来增长在已存在的应用通过提高顾客对更为透明产品的兴趣来增长Reinvigorating and growing polypropylene in existing applications through improved consumer interest and acceptance 4What is Millad NX8000?MilladMillad NX8000 NX8000是一全新分子结构的透明剂是一全新分子结构的透明剂 Millad NX8000 is a
5、 new-to-the-world clarifier based on a new type chemistry that significantly expands the performance of PP clarificationn Millad NX8000Millad NX8000使得透明聚丙烯看使得透明聚丙烯看起来近似聚苯乙烯和聚碳酸酯因而使起来近似聚苯乙烯和聚碳酸酯因而使材料取代成为可能材料取代成为可能 Millad NX8000 allows polypropylene to approach the look and clarity of high clarity pla
6、stics like polystyrene and polycarbonate creating material substitution opportunitiesn 商业级树脂在全球各地都有开发商业级树脂在全球各地都有开发 Commercial grades are in development in each region of the worldHaze Continuum for Selected Plastic MaterialsMilladMillad NX8000 NX8000 使聚丙烯更接近透明工程塑料使聚丙烯更接近透明工程塑料 Millad NX8000 allows
7、PP to close the haze gap on “water white” polymers5PMMAPETPSPCGlassClarified (NX8000) PP(RACO & HOMO)3.5-7.0Clarified PP (1G) RACO20-30Clarified (3G) PP (HOMO)15-20Clarified (3G) PP (RACO) 10-15Clarified (3G) mPP (HOMO)13-16Clarified (3G) mPP (RACO) 9-11Unclarified PP(HOMO) 50-70Unclarified PP (RACO
8、) 40-50Unclarified HDPE 80+“Water White”Clarity (13)Evolutionary Improvements in Polypropylene ClarityNote: 1.25 mm plaquesHaze, %40806020103150 6MilladMillad NX8000 NX8000 的价值何在？的价值何在？What is the Value?提高透明度提高透明度 Improved clarity增宽加工窗口增宽加工窗口 Broad processing window缩短成型周期缩短成型周期 Improved cycle time 7
9、MilladMillad NX8000 NX8000 的价值何在的价值何在？What is the Value?提高透明度提高透明度 Improved clarity增宽加工窗口增宽加工窗口 Broad processing window缩短成型周期缩短成型周期 Improved cycle time 8透明聚丙烯在注塑产品的应用透明聚丙烯在注塑产品的应用Markets for Injection Molded Clear PP 9新一代聚丙烯透明剂有何不同？新一代聚丙烯透明剂有何不同？MilladMillad NX8000 NX8000将将 Millad 3988i Millad 3988i
10、 的雾度降低几乎一半的雾度降低几乎一半 Millad NX8000 gives half the haze as Millad 3988i at any thickness.nMilladMillad NX8000 NX8000 把不同把不同厚度产品的雾度都几乎厚度产品的雾度都几乎降低了一半降低了一半 Millad NX8000 delivers significantly improved haze at all thickness in IM (50%) under commercial conditions nMillad NX8000 Millad NX8000 显著地显著地增宽了加工
11、区间从而使增宽了加工区间从而使得雾度在各种操作条件得雾度在各种操作条件下都接近一致下都接近一致 Millad NX8000 has a significantly broadened processing window - allowing for consistently superior clarity across all polypropylene melt flows and processing conditions要点要点 Points to noteNote: DOEs conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Mil
12、lad NX8000 at 4000 ppm雾度雾度 Haze 10For the Ultimate in Clear Polypropylene 11For the Ultimate in Clear Polypropylene 12MilladMillad NX8000 NX8000 的价值何在？的价值何在？What is the Value?提高透明度提高透明度 Improved clarity增宽加工窗口增宽加工窗口 Broad processing window缩短成型周期缩短成型周期 Improved cycle time 13Parameter LowHighMixingLow
13、Intensity (L)High Intensity (H)ExtrusionSingle Screw (S)Twin Screw (T)Extrusion Temp.190C (L)230C (H)IM Barrel Temp.190C (L)230C (H)IM Injection Rate2.4cc/s (L)30cc/s (H)新一代聚丙烯透明剂有何不同？新一代聚丙烯透明剂有何不同？ What is Next Generation Millad?MilladMillad NX8000 NX8000在各种条件下都能得到好的雾度在各种条件下都能得到好的雾度 A broad process
14、ing window giving excellent haze under all processing conditions.Note: DOEs conducted in 12 MFI RCP; Millad NX8000 at 4000 ppm 14MilladMillad NX8000 NX8000 的价值何在？的价值何在？What is the Value?提高透明度提高透明度 Improved clarity增宽加工窗口增宽加工窗口 Broad processing window缩短成型周期缩短成型周期 Improved cycle time 15MilladMillad NX8
15、000 NX8000结晶温度更高，成型周期更短结晶温度更高，成型周期更短, ,产能提高产能提高 5-10%5-10%Millad NX8000 has a higher Tc and shorter T1/2. When coupled with the broader processing window, productivity enhancements (generally 5 10%) are possible without reducing other quality requirements.Note: Expts conducted in 12 MFI RCP; Millad
16、3988i at 2000 ppm; Millad NX8000 at 4000 ppmTc DataT1/2 Data 16MilladMillad NX8000 NX8000 的价值何在？的价值何在？What is the Value? 提高挤出吹塑产品的透明度提高挤出吹塑产品的透明度EBM - Improved clarity拓宽挤出吹塑的加工窗口拓宽挤出吹塑的加工窗口EBM - Improved processing window 17透明聚丙烯在挤出注塑产品的应用透明聚丙烯在挤出注塑产品的应用Markets for Extrusion Blow Molded Clear PP 18n
17、MilladMillad NX8000 NX8000 使使挤出注塑瓶的外形大挤出注塑瓶的外形大为改观从而加宽了透为改观从而加宽了透明聚丙烯在挤出注塑明聚丙烯在挤出注塑领域的应用领域的应用 Millad NX8000 yields new PP aesthetics in EBM bottles permitting a broader application of cPP in EBM applications.nMillad NX8000 Millad NX8000 在在雾度和光泽度都有显雾度和光泽度都有显著提高著提高 Millad NX8000 gives superior perform
18、ance in haze and gloss at high loadings.MilladMillad NX8000 NX8000显著提高挤出注塑产品的外观显著提高挤出注塑产品的外观Millad NX8000 consistently gives improved aesthetics in EBM要点要点 Points to noteDecreasing loadingNote: Expts conducted in 2 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppm, 500 mL Shampoo bottle雾度
19、雾度 Haze内部光泽度内部光泽度 Inside Gloss 19n硬度略有提高，抗冲硬度略有提高，抗冲击不受影响击不受影响 There is a modest improvement in stiffness without loss in impact resistancen硬度在低温操作条件硬度在低温操作条件下有所提高，抗冲击下有所提高，抗冲击不受影响不受影响 Stiffness is higher at cooler operating temperatures without the loss in impact resistanceMilladMillad NX8000 NX800
20、0具有典型无规共聚的硬度具有典型无规共聚的硬度/ /抗冲击平衡抗冲击平衡Millad NX8000 has typical stiffness/impact balance for RCP. 要点要点 Points to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 ppmFlexural ModulusGardner Impact 20n优异的重复加工稳定优异的重复加工稳定性性, ,宜于回收利用宜于回收利用 Excellent
21、 multi-pass additive stability indicates regrind stabilityMilladMillad NX8000 NX8000在氧化裂解中具有优良的稳定性在氧化裂解中具有优良的稳定性Millad NX8000 has excellent regrind and visc-breaking stability 要点要点 Points to noteDecreasing loadingNote: Expts conducted in 12 MFI RCP; Millad 3988i at 2000 ppm; Millad NX8000 at 4000 pp
22、mNormal 12 MFICR to 35 MFI 21AttributeMillad NX8000Millad 3988iMilladMillad NX8000 NX8000，其他性质类似其他性质类似Millad 3988iMillad 3988i All other attributes are like Millad 3988i.雾度雾度 Haze大约降低大约降低50%50% 50% reduction in haze业界标准业界标准Industry Standard气味气味 Taste & Odor基本一致基本一致 Similar业界标准业界标准 Industry Standard操
23、作温区操作温区 Processing190 250 C190 250 C210 C210 C注册情况注册情况 Regulatory 全球许可申请中全球许可申请中In progress全球许可全球许可 Globally approved提取物提取物Extraction低低 Low低低 Low硬度硬度Stiffness基本一致基本一致 Similar业界标准业界标准 Standard抗冲击抗冲击Impact基本一致基本一致 Similar业界标准业界标准 Standard发黄问题发黄问题Yellowing没问题没问题 No issues没问题没问题 No issues 22For the Ulti
24、mate in Clear Polypropylene 23NX8000 NX8000 商业化个案研究：更高的透明度在食品包装的价值商业化个案研究：更高的透明度在食品包装的价值The Value of Clarity in Food Storage Containers n 应用：应用： 食品包装食品包装 Application: Food Storage Containersn 加工：注塑加工：注塑 Process: Injection Molding 区域：北美区域：北美 Region: North America 追求高清晰度的动力何在？追求高清晰度的动力何在？ Drivers for
25、higher clarity:n (1) 增加销售增加销售 Increase sales 市场研究表明顾客希望更为透明的食品包装市场研究表明顾客希望更为透明的食品包装 Market research demonstrates that consumers prefer higher clarity in food storage containersn (2) 提高利润率提高利润率 Improve margins市场研究表明顾客愿意为更透明的食品包装市场研究表明顾客愿意为更透明的食品包装付出多一些付出多一些 结果证明了这一点结果证明了这一点 Market research suggests t
26、hat consumers will pay more for higher clarity in food storage containers. It has been proved by market. 24食品包装盒转换食品包装盒转换: :高清晰度导致高利润率高清晰度导致高利润率 Food Storage Conversion: Improve Clarity to Improve MarginsProduct LineSizeClear Base Weight (kg)Clear PP Cost / kg resinClear PP Material Cost / PartSales
27、 Price at RetailerServin Saver2.1 cups (500 mL)0.05$1.870.093$1.99Easy Find Lids2 cups (473 mL)0.05$2.170.109$2.19n 成本增加了2美分 Higher clarity adds less than $0.02 / part in cost (assume a $300/ton upcharge for NX8000)n 零售价增加了20美分 Retail price is $0.20 / part higher for the Easy Find Lids 25商业应商业应用举例用举
28、例：n食品食品容器：容器：高端高端顾客对更高透明度的追求顾客对更高透明度的追求n包装材料：取代高成本塑料包装材料：取代高成本塑料如如聚碳酸酯聚碳酸酯，聚氯乙烯，聚苯乙烯，聚氯乙烯，聚苯乙烯，共共聚聚聚酯聚酯 (PETG)(PETG)等等 n婴儿奶瓶婴儿奶瓶：取代：取代聚碳酸酯聚碳酸酯 成本及内分泌腺的安全考虑成本及内分泌腺的安全考虑 n挤吹塑料瓶：化妆品容器挤吹塑料瓶：化妆品容器等等 26For the Ultimate in Clear Polypropylene 27塑料类型塑料类型价格价格(美元美元/吨吨)Price USD/t密度密度(吨吨/米米3)Density (t/m3)价格价格
29、(美元美元/米米3)Price USD/m3均聚聚丙烯均聚聚丙烯 Homo PP$14500.91305高密度聚乙烯高密度聚乙烯 HDPE$14500.941363共聚聚丙烯共聚聚丙烯-NX8000-NX8000 $16500.91485聚苯乙烯聚苯乙烯 Polystyrene $16001.041664聚氯乙烯聚氯乙烯 PVC - Rigid$16001.2-1.41920-2240聚碳酸酯聚碳酸酯 Polycarbonate$25001.23000Millad NX8000 Millad NX8000 材料取代的经济分析材料取代的经济分析 Millad NX8000 Economics I
30、nter-material substitutionSource: IDES, data for Oct 07 28材料取代商机材料取代商机Material Substitution Opportunitiesn聚苯乙烯类聚苯乙烯类 Styrenics (including SAN, SBC)CDCD盒，杯子，包装等盒，杯子，包装等 CD cases, appliances, cups, packaging取代动力取代动力 Drivers- 成本，抗冲击，持久性成本，抗冲击，持久性 Cost (copolymers), impact, sustainabilityn聚酯聚酯 Polyester
31、s包装，杯子，瓶子包装，杯子，瓶子 Packaging, cups, bottles取代动力取代动力 Drivers - 成本，成本， 手感手感 Cost (PETG), hand/feeln聚碳酸酯聚碳酸酯 Polycarbonate婴儿奶瓶，水瓶，家具，日常用具婴儿奶瓶，水瓶，家具，日常用具Infant feeding bottles, water packaging, furniture, housewares, appliances取代动力取代动力 Drivers 成本及内分泌腺的安全考虑成本及内分泌腺的安全考虑 Cost, BPA endocrine disruptionn聚氯乙烯聚
32、氯乙烯 PVC瓶子瓶子 Bottles 环保考虑环保考虑 Driven by environmental pressure 29Millad NX8000 Millad NX8000 荣获荣获2 2008008年年R&D100R&D100创新奖创新奖nR & D 1 0 0 R & D 1 0 0 创新奖（创新奖（R & D 1 0 0R & D 1 0 0 AwardsAwards）是美国科学技术创新）是美国科学技术创新奖。奖。R&D R&D 是研究与发展（是研究与发展（R e s e a r c h &R e s e a r c h & DevelopmentDevelopment）的缩）
33、的缩写写,100,100是指这一奖项的目的：每年在全球范围内，选出优秀的新技是指这一奖项的目的：每年在全球范围内，选出优秀的新技术、新产品术、新产品100 100 项。项。今年是第今年是第4646届。届。n曾获此奖的著名产品：曾获此奖的著名产品：防锁死刹车系统防锁死刹车系统( (Anti Lock BrakeAnti Lock Brake System, System, 1969) 1969) ，自动取款机，自动取款机(1973) (1973) ，传真机，传真机(1975) (1975) ，液晶显示，液晶显示(1980) (1980) ，紫杉醇抗癌药紫杉醇抗癌药(1993) (1993) ，高
34、清晰电视，高清晰电视(1998)(1998)，等等，等等。nMillad NX8000Millad NX8000的的获获奖奖是透明改性行业对社会贡献的肯定。是透明改性行业对社会贡献的肯定。 30颁奖仪式颁奖仪式 31颁奖仪式颁奖仪式 32总结总结 Conclusionsn一种全新的聚丙烯透明剂已上市一种全新的聚丙烯透明剂已上市 A novel clarifying agent chemistry is launchedn更高的透明度使得聚丙烯能和其他透明塑料竞争更高的透明度使得聚丙烯能和其他透明塑料竞争 Performance will allow polypropylene to compe
35、te with water white amorphous polymers like PVC, PS, PVC, PET and SAN on an aesthetics basisn将使透明聚丙烯更快地增长将使透明聚丙烯更快地增长 Will allow cPP to grow faster as a materialnNX8000NX8000树脂已经商业化树脂已经商业化 NX8000 resin is commercially availablen全球注册正在进行中全球注册正在进行中 All appropriate global chemical & food contact regulatory clearances are either complete or in progress 33谢谢各位THANK YOU
