1、金属有机骨架材料及其金属有机骨架材料及其应用应用研究背景早在20世纪90年代中期，第一类MOFs就被合成出来，但其孔隙率和化学稳定性都不高 目前，已经有大量的金属有机骨架材料被合成，这些金属有机骨架中多数都具有高的孔隙率和好的化学稳定性 金属有机骨架（金属有机骨架（MOFsMOFs）是由含氧、氮等的）是由含氧、氮等的多齿有机配体（大多是芳香多酸和多碱）多齿有机配体（大多是芳香多酸和多碱）与过渡金属离子自组装而成的配位聚合物与过渡金属离子自组装而成的配位聚合物 Omar M.Yaghi received his Ph.D.from the University of Illinois-Urban
2、a(1990)with Professor Walter G.Klemperer.He was an NSF Postdoctoral Fellow at Harvard University(1990-92)with Professor Richard H.Holm.He has been on the faculties of Arizona State University(1992-98)and University of Michigan(1999-2006).His current position is the Jean Stone Professor of Chemistry
3、at UCLA.催化剂催化剂气体储存气体储存吸附分离吸附分离含氮杂环含氮杂环含羧基含羧基含氮杂环与羧基含氮杂环与羧基分层、扩散法分层、扩散法水热法水热法搅拌合成法搅拌合成法多孔性多孔性大比表面积大比表面积结构的多样性结构的多样性MOFs合成方法合成方法特点特点应用应用分类分类Design and synthesis of an exceptionally stable and highly porous metal-organic frameworkThis synthesis is achieved by borrowing ideas from metal carboxylate clus
4、ter chemistry,where an organic dicarboxylate linker is used in a reaction that gives supertetrahedron clusters when capped with monocarboxylates.Li,H.Eddaoudi,M.OKeeffe,M.Yaghi,O.M.Nature 402,276-279(1999)MOF-5一个空腔的结构图MOF-5的层结构图MOF-5的吸附性能Interwoven Metal-Organic Framework on a PeriodicMinimal Surfac
5、e with Extra-Large PoresChen,B.L.Eddaoudi,M.Hyde,S.T.OKeeffe,M.Yaghi,O.M.science 291,1021-1023(2001)Chen,B.L.Eddaoudi,M.Hyde,S.T.OKeeffe,M.Yaghi,O.M.science 291,1021-1023(2001)Systematic Design of Pore Size and Functionality in Isoreticular MOFs and Their Application in Methane StorageEddaoudi,M.Kim
6、,J.Rosi,N.Vodak,D.OKeeffe,M.Yaghi,O.M.science 295,469-472(2002)Hydrogen Storage in Microporous Metal-Organic FrameworksRosi,N.L.Eckert,J.Eddaoudi,M.OKeeffe,M.Yaghi,O.M.science 300,1027-1029(2003)MOF-5的储氢性能78K298KRowsell,J.L.C.Spencer,E.C.Eckert,J.Yaghi,O.M.science 309,1350-1354(2005)Metal Organic Fr
7、ameworks as Adsorbents for Trapping and Preconcentration of Organic PhosphonatesNi,Z.Jerrell,J.P.Cadwallader,K.R.Masel,R.I.Analytical Chemistry 79,1290-1293(2007)In this paper,IRMOF1 is tested as an adsor-bent for preconcentration for the first time using dimethyl meth-ylphosphonate(DMMP)as a test c
8、ase.实验流程图吸附性能富集效果105ppb2030ppbMetalOrganic Framework MIL-101 for High-Resolution Gas-Chromatographic Separation of Xylene Isomers and EthylbenzeneGu,Z.Y.Yan,X.P.Angewandte Chemie-International Edition 49,1477-1480(2010)We show the first fabrication of the MOF-coated capillary column for high-resolution GC separation.we choose MIL-101 as the stationary phase and xylene isomers and ethy-lbenzene(EB)as the targets for separation.分离效果影响因素抗干扰能力
