1、ArNH2NaNO2/HCl0 5oCArN2 ClN2 ClWW=Cl,NO2,SO3HArN2 XArN2 SHO4ArN2 BF4O3SN2 X ,HSO4,BF4ArXArHArNO2ArOHArN2 XArN2 XH2O/HArOH+N2+N2Ar+XH2OArOH2ArOHHArN2 XArOH+ArNNOHRArN2 XArINaIN2+ArN2 X+N2Ar+XIArIArN2 XCuClAr+N2+CuCl2CuCl2+ArCl+CuClArN2XArN2 XCuCl 或或 CuBrArX(X=Cl,Br)ArCNCuCN ArN2 BF4NaBF4ArF+N2+BF3ArN
2、2 X+NaX+ArClArBrArN2 XNaBCl4NaBBr4ArN2 BCl4ArN2 BBr4 ArN2 BF4HBF4ArNO2+N2+BF3ArNH2NaNO2NaNO2Cu+NaFArN2 XArHH3PO2+ArN2ArHH3PO2H+H2PO2+Ar+N2+H2PO2ArH3PO2+H2PO2H2PO2+Ar+N2+2 H2OH3PO3+H3OH2PO2ArN2H2PO2H2PO2OHpH=810OHNNArOHROHNNArRpH=810ArN2 X+ArNNOHArNNOHOHArNNOOOHOArNNOArN NHOHONNArH2OOHNNArHNR2+pH=57N
3、R2NNArNR2RNR2NNArRpH=57ArN2 XNR2ArNNNR2ArNNHNR2NNArH2O-H3OAr NNNHR+ArNNNHRArNNNHR ArNNNHRArNN ClRHN+HArNNNH-HArNNNRRHArNNHONNHOSO3 NaOH NH2NNNNNaO3SSO3NaNO2ArSO3HNaOH300oCArH+OHH3CBrSO3HH3CBrOH1.NaOH/300oC2.H+H3COHBr2?H3CH3CBrOHH3CBrOHH3CBrN2 SO4HH3CBrNH2H3CBrNO2H3CNO2H3CH3CBrOHH3CBrNH2H3CBrNO2H3CNO
4、2H3CHNO3H2SO4Br2FeFeHBrNaNO2H2SO4H2O/HH3CBrN2 SO4H BrBrBrBr2FeBrBr2FeBrBrBrBr+BrBrBrBrBrBrNH2NH2HNO3H2SO4FeHClNaNO2/HClBrBrBrBr2（过过量量）H2OBrBrBrNH2NH20-5oCBrBrBrN2 ClH3PO2CH3CH3BrCH3CH3BrCH3BrNH2CH3NHCOCH3NaNO2/HCl0-5oCH3PO2H2O/H+CH3BrCH3BrNH2CH3HNO3H2SO4FeHClCH3NH2Ac2OEt3NCH3NHCOCH3CH3BrN2 ClCH3NO2C
5、H3NHCOCH3FeBr2BrCH3FBrCH3IBrBrBrBrCH3CH3NO2CH31.2.3.R4N OHR4N XAg2O或或 AgOH+AgXNCH2H3CCH3CH3CRCH2CHR+H H2OOHNH3CCH3CH3H+主主要要NaOC2H5CH2CHH3CCHCH2X HHCH2CHH3CCHCH2HCH2CHH3CCHCH2N(CH3)3 OHCH2CHH3CCHCH2CH2CHH3CCHCH298%2%+HHHH NCH2H2CCH3CH3CH2HCH3COHCH2CH2+HHNH2CCH3CH3H2CH3C 主主要要产产物物 CH2N(CH3)3 OHCH2CH2+9
6、9%1%CH2CHCH3CHCH2N(CH3)3 ICH2CHCH3CHCH296%NaOC2H5,HOC2H5HHHHHHH (H3C)3NCCHOH(H3C)3NCCHOH CC OHRCHCHCH2N(CH3)3HH CH2CH3N(CH3)3 OHCH3N(CH3)3ICH3NH2CH3CNH2OCH2CH3CNH2OCH3NH2Br2/NaOH3 CH3ICH3N(CH3)3IAgOHCH3N(CH3)3 OH PhCH2CH2NCH2CH3CH3CH3OHCHCH2Ph93%CH2CH2+0.4%CH3N(CH3)3OH CH3+N(CH3)3NCH3NCH3HHNCH3HNCH3
7、CH3CH3IAg2ONCH3CH3CH3OHNCH2CH3CH3彻彻底底甲甲基基化化彻彻底底甲甲基基化化Ag2O CH3I2 CH3I NCH3HAg2ONCH3CH3CH3CH32 CH3I彻彻底底甲甲基基化化 人有了知识，就会具备各种分析能力，人有了知识，就会具备各种分析能力，明辨是非的能力。明辨是非的能力。所以我们要勤恳读书，广泛阅读，所以我们要勤恳读书，广泛阅读，古人说古人说“书中自有黄金屋。书中自有黄金屋。”通过阅读科技书籍，我们能丰富知识，通过阅读科技书籍，我们能丰富知识，培养逻辑思维能力；培养逻辑思维能力；通过阅读文学作品，我们能提高文学鉴赏水平，通过阅读文学作品，我们能提高文学鉴赏水平，培养文学情趣；培养文学情趣；通过阅读报刊，我们能增长见识，扩大自己的知识面。通过阅读报刊，我们能增长见识，扩大自己的知识面。有许多书籍还能培养我们的道德情操，有许多书籍还能培养我们的道德情操，给我们巨大的精神力量，给我们巨大的精神力量，鼓舞我们前进鼓舞我们前进。
