离子液体及其在催化合成中的最新进展课件.ppt

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1、Ionic Liquid ILsDr MAHMOUD Najim Abid&Taghreed M.Musa PPT 2019 One of the main directions of the global research,is the search for new chemical compounds with special,properties.Ionic liquids are such compounds Their application brings new,possibilities for modern chemical technology.The ionic liqui

2、ds,fit,well,in the assumptions of green chemistry.In contrast to the previous approach,the green chemistry requires design,development and implementation of new processes and chemicals that allow the reduction or elimination of use and production of hazardous,materials.Twelve principles of green che

3、mistry formulated in 1998 by Anastas and Warner describe the methods of implementation of these tasks.Ionic liquids meet at least three of these principles(safer solvents)(provide energy efficiency)and no.9 (are used in catalytic reactions).Ionic liquid precursors are quaternary ammonium halides kno

4、wn from the 1890s,which were widely used and tested in the 20th century.The history of synthesis and application of organic salts containing a quaternary nitrogen atom is presented*The description of a low melting point salt-1914Ethyl ammonium nitrate*The first room temperature ionic liquid-1951N-et

5、hylpyridinium bromide-aluminium chloride melt*The most stable and conductive salts-19821,3-dialkylimidazolium salts*The hydrophobic ionic liquids-19921-ethyl-3-methylimidazolium tetrafluoroborateDiscovery and HistorySeveral experiments have conducted to prepare ionic liquids used different types of

6、Amines components as Ethanolamine,Urea,Acetamide,Thiourea and Thioacetmide,with aluminum salt as Aluminum Chloride,Aluminum nitrate,Ammonium Sulfate,Potassium Aluminum Sulfate and Aluminum Stearate.Some of these attempts have produced results using varying temperatures of up to 80C and other auxilia

7、ry factors.Some physical characteristics such as ionic conductivity and melting point.FT-IR and electronic spectra and cyclic voltametry measurements have investigatedDevelopmentSolvents classificationOrganic solvents involve Vander Walls interactionWater Hydrogen bondingIonic Liquids involves colum

8、bic interactions between assymetric cationAnd symmetric anions like BF4-,PF6-,ClO4-The asymmetry of cations in the structure of Ils will prevent the packingOf ions and no lattice as shown in ionic compounds and this unique Properties makes the Ils have extreme physical and chemical propertiesAnd the

9、n it is called future and green solvents What are Ionic LiquidsIonic liquid in synthesisIonic Liquids are ionic compounds(salts)whichare liquid below 100.More commonly,Ionic Liquids have melting points below roomtemperature.The Ils produced as liquids in the room temperature could be called RTILs or

10、 Eutectic solvents and may be characterized with their viscosity,ionic conductivity and wide electrochemical windows in addition to their thermal stability on the basis of TG-DSC studies.Synthesis of Ionic Liquids As stated in previous section(1:1),the first room temperature ionic liquid EtNH3 NO3(m

11、.p.12 C)was discovered in 1914,but interest did not develop until the discovery of binary ionic liquids made from mixtures of aluminum(III)chloride and N-alkylpyridinium or 1,3-dialkylimidazolium chloride.Ionic liquids come in two main categories,namely,simple salts(made of a single anion and cation

12、)and binary ionic liquids(salts where equilibrium is involved).For example,EtNH3NO3 is a simple salt whereas mixtures of aluminum(III)chloride and 1,3-dialkylimidazolium chlorides(a binary ionic liquid system)contain several different ionic species,and their melting point and properties depend upon

13、the mole fractions of aluminum(III)chloride and 1,3-dialkylimidazolium chloride present.The synthesis of ionic liquids can be described in two stepsMain routes to prepare Ionic Liquids:1-Acid base reactions like thiourea with salts of Calcium or alumium 2-Solvation of active organic compounds like c

14、itrazine,triacetic acid with some metal salts3-Metathesis reactions which involves the displacement reactions4-Alkylation of heterocyclic compounds like pyridine,pyrrolidine and imidazole with R-X followed metathesis reaction by salts ofKPF6,KBF4 and metal perchlorate or bromate5-Rare reactions of c

15、helation which are almost occurred in the case of 18-crown-6 with K+and Li+ions then fast metathesis with symmetric anions of PF6-,CF3COO-and BF4-.Preparation of pyrrolidinium saltsCommon DefinitionnIonic Liquids(ILs)is the generic term for a class of materials,consisting entirely of ions and being

16、liquid below 100C.nIf they are liquid at room temperature,we call them room temperature ionic liquids(RTILs).Typical Cation and AnionNRNNR1R2*PF6-for moisture stable,water immiscible IL*BF4-for moisture stable,but water miscible IL*AlCl4-(or other Lewis acids)decomposes in waterApplicationAdvantageE

17、asy separationVery low vapor pressureNon-flammable substanceHigh thermally stableHigh mechanically stableElectrochemically stableLow toxicityNon-volatilityIonic Liquids in Organic SynthesisCatalytic HydrogenetionsHydroformylationsHeck reactionsSuzuki couplingStille CouplingFriedelCraftsAlkoxycarbony

18、lationOlefin dimerizationDiels-AlderOxidationsDiels-Alder reactionHeck ReactionWittig reactionSuzuki-Miyaura coupling reactionStille reactionFriedel-Crafts reactionHydrogenationFluorinationReactionWe can in the future research1.Prepare a new ionic liquids by mixing the other aluminum M=Zn,Sn,Fe,Al,G

19、a,Ca,salts with organic compound.2.Study the status stereochemistry and geometric shape of ionic liquids prepared3.Study the possibility of using ionic liquids as an antibiotic or with other pharmaceuticals.4.The possibility of studying the effect of ionic fluids on hormones and cancer tumors5.The t

20、oxic influence of ILs may be associated to a common cellular structure or processConclusionIonic liquids,as the new materials of multifunction,are widely used in various of fields.Environmently-friendly reaction process have vigorously been studied from the standpoint of green chemistry and based on the properities of easy separation,low toxicity,selective miscibility,ILS play an important role in organic synthesis as the green alternative solvent.Withe the development of multifunctional ILS,we can expect IlS would apply in more fields.

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