1、YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程 YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程 YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程 YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程 1Ox0c2Red0c0Red0Ox0VVbf21ccaba0Red0spOx0VV21ccYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程 YANGTZE NORMAL
2、UNIVERSITY重庆市精品课程重庆市精品课程0.68VE0/FeFe231.44VE0/CeCe34TFeTFe0/FeFe23230.059lgEEccTCeTCe0/CeCe34340.059lgEccYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程各滴定点电位的计算方法如下:各滴定点电位的计算方法如下:YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程)1.200(mmol12.000.1000VV)(443CeCeFecc44222CeCeFeFeFeVVV)(ccc剩余12.00)000.1000(20.)0.800(mm
3、ol8.000.1000YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程TFeTFe0/FeFe23230.059lgEEcc0.801.200.059lg0.680.69(V)2233FeFeFeFeVV0.059lg0.68ccYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程60%100%20.0012.00Fe340%100%20.0012.0020.00Fe2TFeTFe0/FeFe23230.059lgEEcc0.69(V)40600.059lg0.68YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精
4、品课程2323FeFe0/FeFespcc0.059lgEE3434CeCe0/CeCespcc0.059lgEETCeTFeTCeTFesp3243cccc0.059lg1.440.682ETCeTCe34cc0.059lg1.44TFeTFe23cc0.059lg0.68YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程33CeFecc42CeFecc0cccclgTCeTFeTCeTFe32431.06(V)21.440.68EspYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程01E02E11RedOx101spclgn0.05
5、9EEc11RedOx011sp1cc0.059lgEnEnYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程2121RedRedOxOx022011sp210.059lgEnEn)En(ncccc21RedOxcc12RedOxcc0lgTRedTRedTOxTOx2121cccc22RedOx202splgn0.059EEcc22RedOx022sp20.059lgEnEnccYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程21022011spnnEnEnEYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课
6、程22444FeFeCeCeCeVcVc(cV)过量20.0020.020.1000)0.002(mmol244FeCeCeVVcYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程22333FeFeCeCeCeVcVc(cV)TCeTCe0/CeCe3434cc0.059lgEE33CeCe101011000.1cc34)2.000(mmol20.000.10001.26(V)2.0000.0020.059lg1.44YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程TCeTCe0/CeCe3434cc0.059lgEE 1.26(V)0
7、.059lg(101.443YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程7-1YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程21022011spnnEnEnE01E02EYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程101202n0.0593En0.0593E YANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程23Sn2Fe42Sn2Fe0.70VE0/FeFe230.14VE0/SnSn240.33(V)210.1420.701EspYANGTZE NORMAL UNIVERSITY重庆市精品课程重庆市精品课程0.52(V)10.0593-0.700.23(V)20.05930.14