1、Reactions of CarbonNucleophiles with CarbonylCompoundsProf.Yue Chen(陈 悦)Oct.31th,20082.4.1.1.Olefination Reactions Involving Phosphonium Ylides2.4.1.1.Olefination Reactions Involving Phosphonium Ylides2.4.1.2.Olefination Reactions Involving Phosphonate Anions2.4.1.2.Olefination Reactions Involving P
2、hosphonate Anions.2.4.1.2.Olefination Reactions Involving Phosphonate Anions.2.4.1.2.Olefination Reactions Involving Phosphonate Anions.2.4.1.2.Olefination Reactions Involving Phosphonate Anions.2.4.1.2.Olefination Reactions Involving Phosphonate Anions.2.4.1.2.Olefination Reactions Involving Phosph
3、onate Anions.2.4.2.Reactions of-Trimethylsilylcarbanions with Carbonyl CompoundsPeterson reaction2.4.2.Reactions of-Trimethylsilylcarbanions with Carbonyl CompoundsHSi(CH3)3ROArHLi2.4.2.Reactions of-Trimethylsilylcarbanions with Carbonyl Compounds2.4.2.Reactions of-Trimethylsilylcarbanions with Carb
4、onyl Compounds2.4.2.Reactions of-Trimethylsilylcarbanions with Carbonyl Compounds2.4.3.The Julia Olefination Reaction2.4.3.The Julia Olefination Reaction2.4.3.The Julia Olefination Reaction2.5.Reactions Proceeding by Addition-Cyclization2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides
5、 and Related Nucleophiles2.1.2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.1.S
6、ulfur Ylides and Related Nucleophiles2.5.1.Sulfur Ylides and Related Nucleophiles2.5.2.Nucleophilic Addition-Cyclization of-Haloesters2.5.2.Nucleophilic Addition-Cyclization of-Haloesters2.6.Conjugate Addition by Carbon Nucleophiles2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enol
7、ates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.1.Conjugate Addition of Enolates2.6.2.Conjugate Addition with Tandem Alkylat
8、ion2.6.3.Conjugate Addition by Enolate Equivalents2.6.3.Conjugate Addition by Enolate EquivalentsA tendency to favor anti diastereoselectivity,regardless of the silyl enol ether configuration2.6.3.Conjugate Addition by Enolate Equivalents2.6.4.Control of Facial Selectivity in Conjugate Addition Reac
9、tions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.4.Control of Facial Selectivity in Conjugate Addition Reactions2.6.5.Conjugate Addition of Organometallic Reagents2.6.6.Conjugate Addition of Cyanide Ion2.6.6.Conjugate Addition of Cyanide Ion
