1、CH2CH CH2ClCHClCH2CHClCH2CHClCH2CHClnCH2CHClmCH2CHOCOCH3nCH2CH2nCH2CH2n CH2CHClnNH2(CH2)6NH2+ HOOC(CH2)4COOHNH(CH2)6NHCO(CH2)4COnNH(CH2)6NHCO(CH2)4COnCH2CHClnSiCH3CH3OnNPClClnOCH2CH2nCH2CHOHnH2CCH2OHCH2CHnOCORNH(CH2)6NHCO(CH2)4COnRNHCORnRNHCONHRnRSOORnROCORnSiCH3CH3OnClSiCH3CH3ClSiCH3CH3OnH2OHO SiCH
2、3CH3OHnnCH2CHClnH2CCHCHCH2ClClHCCH2CH2CHClClH2CCHCH2CHClClCH2CHCHCH2CHCHCH2CH2CH2CHCHCH2CH2CHCHCH2H3CCH2CHCHCH2CH2CHCHCH2CH3 M1M2M2M1M2M1M1M1M2M1M1M2M1M1M2M1M2M1M2M1M2M1M2M1M2M1M1M2M1M2M1M2M1M2M1M2M1M2M1M1M1M1M1M1M1M1M1M1M1M1M1M1M2M2M2M2M2M2M2n Br(CH2)10Br+2n NaCH2CH25n+ 2n NaBrn CH2N2CH2CH2n/2+ n N
3、2C？AIBNAIBNNCCNCH3CH3NCCH3CNCH3CCH3CNCH3+N2OOOOOO2+2CO2I2RR+CH2CH2XR CH2CHXRCH2CHXCH2CHXRCH2CHCH2CHXXRCH2CHXCH2CHXCH2CHnXM1M2M3MxMMMCH2CHX+CHCH2XCH2CCCH2XXHHCH2CHX+CHCH2XCH2CH2+CHCHXXCH2CH2XRCH2CHXRCH2CH2XCH2CHX+CH3CHXCH2CHX+CH2CH2XCH2CH2XCHCl3CCl3CH2CHXMxHCH3CHMx+XCH2CHXI2CH2CHX I+ II22R+M1M2RM1RM2
4、R链引发+M1M1M1M1+M1M2M1M2 RM+MRMMRMxkp+MMMMxMMMxnC4H9Li+CHCH2nC4H9CH2CHLin-C4H9CH2CHn+ CH3OHCH3OLin-C4H9CH2CHnH+Li+CHCH2nC4H9CH2CHLi(n-1)n-C4H9CH2CHnLi： RMxLiCH3OHRMxH+ CH3OLiRMxLi +(CO2,H2 O)RMxOH(RMxCOOH)RMxLi +ORMx(CH2)4O-Li+COOHOHCOO1-p1-pnw+H2O+p= K=2OHCOOHOHCOO2)1 (ppnwp11pnwkp1kXn= = =H2CCH2COO-
5、COONH2COO-H2CCHClClClClClZnH2CClCHnCH2OHCH2CHmNHCOCHSNCHCHCOCH3CH3NH2CHnCH2CH2CHmNHCOCHSNCHCHCOCH3CH3NH3NO CH2CCH2CH2CH3CHRRRR+ CH2CH2CH2CHClCH2CHClCH2CHClCH=CHCH=CHCH=CHHClCH2CHClCH2CHClCH2CHCH2CHCH2CHCH2CHCH2CHCH2CH+ CH2OHCOOH- H2OCH2COCCH2OOOHOCH2COOHnCH3CHOHCOOH- H2OCHOCHOCH3H3CHCCH3COnOOCHCCH3OOCHHCOmn CCHHClH聚氯乙烯O环己酮+-+OCCH3CH3OCOCHCl2H+-氢键1 12212iiniiiiiiM nM nMnMnnnMnNMn2iiiiwiiiWMnMMWnM1/iaaiiWMMM=kM MnMwMMwMMn 温度，C形变L/L，%IIIIIIIVVTgTfTd Tg= niTgi ni： 经验公式经验公式:Tg/Tm 1/2 Tg/Tm 2/3
